Newly Found Digital Memory Characteristics of Pyrrolidone- and Succinimide-Based Polymers.

This study reports for the first time the excellent nonvolatile and volatile digital memory characteristics of polymers bearing 2-pyrrolidone and succinimide moieties. A series of new polymers is synthesized from poly(ethylene-alt-maleic anhydride) and four alcohol derivatives with and without 2-pyrrolidone and succinimide moieties. All polymers, including polyvinylpyrrolidone, are found to be thermally stable up to 195 °C or higher, and characterized regarding their molecular orbital energy levels, bandgap, and resistive digital memory behaviors. Excitingly, the polymers bearing either 2-pyrrolidone or succinimide moiety demonstrate p-type digital memory behaviors with high ON/OFF current ratios and long reliabilities. Nonvolatile digital memory performance is achieved over the film thickness range of 10-80 nm, whereas volatile digital memory is demonstrated over a much narrower range of film thickness. All digital memory performances can be originated from the 2-pyrrolidone and succinimide moieties possessing high affinity and stabilization power to charges via charge traps and transformations based on a hopping conduction process. Hence, these new polymers are suitable for the production of high-performance p-type nonvolatile and volatile digital memory devices. Moreover, 2-pyrrolidone and succinimide can be used as new and economical electroactive building blocks for the development of advanced digital memory materials.

Full-field thickness measurement of ultrathin liquid film in receding contact-induced nano-channel using surface plasmon resonance.

This research demonstrates that a surface plasmon resonance (SPR) imaging technique can effectively measure full-field nanoscale thickness of a liquid water film filled in the receding contact-induced nano-channel. To the authors' knowledge this has not been demonstrated previously. Experimental calibration has been conducted by measuring surface plasmon resonance reflectance depending on the piezometer-controlled water nano-film thickness and comparing the experimental results with the theoretical calculations to show very good agreement. The measured full-field thickness profiles significantly visualize the three-dimensional nano-channel formation filled with liquid water film. It shows that the sensitivity and the resolution in thickness measurement are estimated as 1.21 pixel gray level/nm and 2.5 nm, respectively. The experimentally observed resolution is around 10 nm given the uncertainty in the demonstrated full-field mapping of thickness. From this research, it is demonstrated that SPR imaging successfully measures the thickness of ultrathin liquid film especially below 85 nm in full-field under normal conditions and can effectively characterize the three-dimensional nano-channel formation during the receding contact process.