Upper critical solution temperature (UCST) phase transition of halide salts of branched polyethylenimine and methylated branched polyethylenimine in aqueous solutions.

The upper critical solution temperature (UCST) phase transition of halide salts of branched polyethylenimine (PEI) and methylated branched polyethylenimine (MPEI) is first reported in aqueous solutions. In particular, iodide counter-ions can introduce UCST properties in MPEI. The importance of the counter-ion composition of MPEI for UCST transition is discussed in detail.