1.
ChemSusChem
; 5(9): 1787-92, 2012 Sep.
Artigo
em Inglês
| MEDLINE
| ID: mdl-22761058
RESUMO
An original two-step process efficiently catalyzed by functionalized mesoporous materials is proposed as a potential route for converting light olefins into long-chain hydrocarbons in the distillate range. In the first step, ethylene can be selectively transformed into C4 -C10 olefins with an even number of carbon atoms, over nickel-exchanged AlMCM-41, at 150 °C. When the nickel-catalyzed oligomerization was assisted by a second acid-catalyzed step over H-MCM-41, olefins with chains longer than 10 carbon atoms were mainly produced with a productivity of 180â g g⻹ h⻹.