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RATIONALE: The isotope ratio for the internationally agreed but virtual zero-point of the carbon isotope-delta scale, Vienna Peedee belemnite (VPDB), plays a critical role in linking carbon isotope delta values to the SI. It is also a quantity used for various data processing procedures including '17O correction', clumped isotope analysis and conversion of carbon isotope delta values into other expressions of isotopic composition. A value for RVPDB(13C/12C) with small uncertainty is therefore desirable to facilitate these procedures. METHODS: The value of RVPDB(13C/12C) was determined by errors-in-variables regression of isotope delta values traceable to VPDB measured by isotope ratio mass spectrometry against isotope ratios traceable to the SI by use of gravimetric mixtures of 12C- and 13C-enriched d-glucose measured by multicollector inductively coupled plasma mass spectrometry. RESULTS: A value of RVPDB(13C/12C) = 0.0111105 ± 0.0000042 (expanded uncertainty, k = 2) was obtained. CONCLUSIONS: The new value for RVPDB(13C/12C) agrees very well with the consensus values calculated from previous measurement results proposed by Kaiser and by ourselves, as well as recent determinations independent of mass spectrometry. The expanded uncertainty of 0.4 when expressed as an isotope delta value is a tenfold improvement over the previous best measurement of the isotopic composition of carbon.
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RATIONALE: The oxygen and hydrogen isotope compositions of the water component of the milk from nine Italian dairy farms were studied together with the farm water for one year. The aim was to verify the importance of farm water and seasonal temperature variation on milk isotope values and propose mathematical relations as new tools to identify the milk origin. METHODS: Milk was centrifuged to separate the solids and then distilled under vacuum to separate water. δ(18 O/16 O) and δ(2 H/1 H) analyses of the water molecules were carried out using a water equilibrator online with a mass spectrometer. For oxygen and hydrogen isotope determination, water was equilibrated with pure CO2 for 7.5 h and with pure H2 for 5 h, respectively. The isotope ratio value is indicated with δ (expressed on the VSMOW/SLAP scale) as defined by IUPAC. RESULTS: The average annual isotope value of milk at the different cattle sheds is mostly related to the farm water suggesting that the drinking water is the most important factor influencing the isotopic values of the milk water. The milk/water fractionation factor correlates with the milking time and, thus, the seasonal temperature is best described by a 4th order polynomial regression line. A two-level check model was used to verify the milking provenance. CONCLUSIONS: This study shows that it is essential to analyze both milk and farm water to indicate provenance. A two-step verification tool, based on the difference between the measured and calculated δ(18 O/16 O)M values, and the difference between the calculated and estimated milk-water fractionation factors, allowed the source determination of milk. Both conditions must be met if the milk is considered to be from the Parmigiano-Reggiano production region. Although this approach was developed for this region, it can easily be tested and adapted to other dairy production areas.
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Deutério/análise , Água Doce/química , Leite/química , Isótopos de Oxigênio/análise , Animais , Bovinos , Análise Discriminante , Fazendas , Feminino , Itália , Espectrometria de Massas , Controle de Qualidade , Estações do AnoRESUMO
The maternal diet and living environment can affect levels of chemical elements and fatty acid (FA) composition and their stable isotopes (δ13CFA) in human milk. Information obtained from questionnaires is frequently imprecise, thus limiting proper associations between external and internal exposures as well as health effects. In this study, we focused on seafood as a source of potentially toxic and essential elements and nutritional FAs. Concentrations of selected elements in human milk (As, Cd, Cu, Mn, Pb, Se and Zn) were determined using inductively coupled plasma mass spectrometry (ICP-MS) and Hg using cold vapour atomic-absorption spectrometry (CV-AAS). The identification and quantification of FAs in maternal milk were performed by an in-situ trans-esterification method (FAMEs), and the characterization of FAMEs was performed by gas chromatography with a flame ionisation detector (GC-FID). δ13CFA was determined by gas chromatography-combustion-isotope ratio mass spectrometry (GC-C-IRMS). Seventy-four lactating Slovenian women from the coastal area of Koper (KP), with more frequent consumption of seafood, and the inland area of Pomurje (MS), with less frequent seafood consumption, were included in this study. Along with basic statistical analyses, data mining approaches (classification and clustering) were applied to investigate whether FA composition and δ13CFA could improve the information regarding dietary sources of potentially toxic elements. As and Hg levels in milk were found to be statistically higher in populations from KP than in those from MS, and 71% of individual FAs and 30% of individual δ13CFA values in milk differed statistically between the studied areas. In 19 cases, the levels of FAs in milk were higher in KP than in MS; these FAs include C20:5ω3 and C22:6ω3/C24:1ω9, which are typically contained in fish. In 16 cases, the mean percentage of FAs was higher in MS than in KP; these FAs include the PUFAs C18:2ω6, C18:3ω3, and C20:4ω6 which are important for human and infant growth. The difference in δ13C levels of C10:0, C12:0, C14:0, C16:1, C16:0, C18:1ω9c, C22:6ω3, and δ13C 18:0-16:0 in the study groups was statistically significant. In all seven cases where δ13C of FA significantly differed between KP and MS, δ13C was higher in KP, indicating a higher proportion of a marine-based diet. The data mining approaches confirmed that the percentage of selected FAs (iC17:0, C4:0, C18:2ω6t, aC17:0, CLA, and C22:4ω6) and δ13CFA of C18:1ω9c in human milk could be used to distinguish between high and low frequency of fresh seafood consumption.
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Exposição Dietética/estatística & dados numéricos , Lactação , Exposição Materna/estatística & dados numéricos , Leite Humano , Alimentos Marinhos/estatística & dados numéricos , Animais , Ácidos Graxos , Comportamento Alimentar , Feminino , Cromatografia Gasosa-Espectrometria de Massas , Humanos , LeiteRESUMO
Today, the analytical verification of food safety and quality together with authenticity and traceability plays a central role in food analysis [...].
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Análise de Alimentos/instrumentação , Análise de Alimentos/métodos , Tecnologia de Alimentos , Alimentos , Isótopos , Inocuidade dos Alimentos , Humanos , FenóisRESUMO
This study examined the percentage and stable isotope ratios of fatty acids in milk to study seasonal, year, and regional variability. A total of 231 raw cow milk samples were analyzed. Samples were taken twice per year in 2012, 2013, and 2014, in winter and summer, covering four distinct geographical regions in Slovenia: Mediterranean, Alpine, Dinaric, and Pannonian. A discriminant analysis model based on fatty acid composition was effective in discriminating milk according to the year/season of production (86.9%), while geographical origin discrimination was less successful (64.1%). The stable isotope composition of fatty acids also proved to be a better biomarker of metabolic transformation processes in ruminants than discriminating against the origin of milk. Further, it was observed that milk from Alpine and Mediterranean regions was healthier due to its higher percentage of ω-3 polyunsaturated fatty acid and conjugated linoleic acid.
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Isótopos de Carbono/análise , Ácidos Graxos/análise , Geografia , Leite/química , Estações do Ano , Animais , Bovinos , Análise por Conglomerados , Análise Discriminante , EslovêniaRESUMO
This paper summarises the isotopic characteristics, i.e., oxygen and hydrogen isotopes, of Slovenian milk and its major constituents: water, casein, and lactose. In parallel, the stable oxygen isotope ratios of cow, sheep, and goat's milk were compared. Oxygen stable isotope ratios in milk water show seasonal variability and are also 18O enriched in relation to animal drinking water. The δ18Owater values were higher in sheep and goat's milk when compared to cow milk, reflecting the isotopic composition of drinking water source and the effect of differences in the animal's thermoregulatory physiologies. The relationship between δ18Omilk and δ18Olactose is an indication that even at lower amounts (>7%) of added water to milk can be determined. This procedure once validated on an international scale could become a reference method for the determination of milk adulteration with water.
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Hidrogênio/análise , Leite/química , Isótopos de Oxigênio/análise , Animais , Caseínas/química , Bovinos , Geografia , Água Subterrânea/química , Lactose/análise , Padrões de Referência , Estações do Ano , EslovêniaRESUMO
In this work, fatty-acid profiles, including trans fatty acids, in combination with chemometric tools, were applied as a determinant of purity (i.e., adulteration) and provenance (i.e., geographical origin) of cosmetic grade argan oil collected from different regions of Morocco in 2017. The fatty acid profiles obtained by gas chromatography (GC) showed that oleic acid (C18:1) is the most abundant fatty acid, followed by linoleic acid (C18:2) and palmitic acid (C16:0). The content of trans-oleic and trans-linoleic isomers was between 0.02% and 0.03%, while trans-linolenic isomers were between 0.06% and 0.09%. Discriminant analysis (DA) and orthogonal projection to latent structure-discriminant analysis (OPLS-DA) were performed to discriminate between argan oils from Essaouira, Taroudant, Tiznit, Chtouka-Aït Baha and Sidi Ifni. The correct classification rate was highest for argan oil from the Chtouka-Aït Baha province (90.0%) and the lowest for oils from the Sidi Ifni province (14.3%), with an overall correct classification rate of 51.6%. Pairwise comparison using OPLS-DA could predictably differentiate (≥0.92) between the geographical regions with the levels of stearic (C18:0) and arachidic (C20:0) fatty acids accounting for most of the variance. This study shows the feasibility of implementing authenticity criteria for argan oils by including limit values for trans-fatty acids and the ability to discern provenance using fatty acid profiling.
Assuntos
Cosméticos/análise , Cosméticos/química , Ácidos Graxos/química , Óleos de Plantas/análise , Óleos de Plantas/química , Cosméticos/normas , Ácido Linoleico , Marrocos , Ácido Oleico , Ácido PalmíticoRESUMO
This study used elemental and stable isotope composition to characterize Slovenian truffles and used multi-variate statistical analysis to classify truffles according to species and geographical origin. Despite the fact that the Slovenian truffles shared some similar characteristics with the samples originating from other countries, differences in the element concentrations suggest that respective truffle species may respond selectively to nutrients from a certain soil type under environmental and soil conditions. Cross-validation resulted in a 77% correct classification rate for determining the geographical origin and a 74% correct classification rate to discriminate between species. The critical parameters for geographical origin discriminations were Sr, Ba, V, Pb, Ni, Cr, Ba/Ca and Sr/Ca ratios, while from stable isotopes δ18O and δ13C values are the most important. The key variables that distinguish T.magnatum from other species are the levels of V and Zn and δ15N values. Tuber aestivum can be separated based on the levels of Ni, Cr, Mn, Mg, As, and Cu. This preliminary study indicates the possibility to differentiate truffles according to their variety and geographical origin and suggests widening the scope to include stable strontium isotopes.
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Ascomicetos/química , Metais/análise , Solo/química , Ascomicetos/crescimento & desenvolvimento , Isótopos de Carbono/análise , Isótopos de Carbono/metabolismo , Metais/metabolismoRESUMO
RATIONALE: Analytical methods that can identify the source and fate of mercury and organomercury compounds are likely to be useful tools to investigate mercury in the environment. Carbon isotope ratio analysis of methylmercury (MeHg) together with mercury isotope ratios may offer a robust tool to study environmental cycling of organomercury compounds within fish tissues and other matrices. METHODS: MeHg carbon isotope ratios were determined by gas chromatography/combustion-isotope ratio mass spectrometry (GC/C-IRMS) either directly or following derivatization using sodium tetraethylborate. The effects of a normalization protocol and of derivatization on the measurement uncertainty of the methylmercury δ13 CVPDB values were investigated. RESULTS: GC/C-IRMS analysis resulted in a δ13 CVPDB value for an in-house MeHg reference material of δ13 CVPDB = -68.3 ± 7.7 (combined standard uncertainty, k = 1). This agreed very well with the value obtained by offline flow-injection analysis/chemical oxidation/isotope ratio mass spectrometry of δ13 CVPDB = -68.85 ± 0.17 (combined standard uncertainty, k = 1) although the uncertainty was substantially larger. The minimum amount of MeHg required for analysis was determined to be 20 µg. CONCLUSIONS: While the δ13 CVPDB values of MeHg can be obtained by GC/C-IRMS methods with or without derivatization, the low abundance of MeHg precludes such analyses in fish tissues unless there is substantial MeHg contamination. Environmental samples with sufficient MeHg pollution can be studied using these methods provided that the MeHg can be quantitatively extracted. The more general findings from this study regarding derivatization protocol implementation within an autosampler vial as well as measurement uncertainty associated with derivatization, normalization to reporting scales and integration are applicable to other GC/C-IRMS-based measurements.
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Forensic application of carbon isotope ratio measurements of honey and honey protein to investigate the degree of adulteration with high fructose corn syrup or other C4 plant sugars is well established. These measurements must use methods that exhibit suitable performance criteria, particularly with regard to measurement uncertainty and traceability - low levels of adulteration can only be detected by methods that result in suitably small measurement uncertainties such that differences of 1 or less can be reliably detected. Inter-laboratory exercises are invaluable to assess the state-of-the art of measurement capabilities of laboratories necessary to achieve such performance criteria. National and designated metrology institutes from a number of countries recently participated in an inter-laboratory assessment (CCQM-K140) of stable carbon isotope ratio determination of bulk honey. The same sample material was distributed to a number of forensic isotope analysis laboratories that could not participate directly in the metrological comparison. The results from these studies have demonstrated that the majority of participants provided isotope delta values with acceptable performance metrics; that all participants ensured traceability of their results; and that where measurement uncertainties were reported; these were fit-for-purpose. A number of the forensic laboratories only reported precision rather than full estimates of measurement uncertainty and this was the major cause of the few instances of questionable performance metrics. Reporting of standard deviations in place of measurement uncertainties is common practice outside metrology institutes and the implications for interpretations of small differences in isotopic compositions are discussed. The results have also highlighted a number of considerations that are useful for organisers of similar inter-laboratory studies in the future.
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Isótopos de Carbono/análise , Ciências Forenses/métodos , Mel/análise , Laboratórios , Incerteza , Internacionalidade , Reprodutibilidade dos TestesRESUMO
Slovenia, influenced by Slavic, Mediterranean, and Balkan cultures, along with Austro-Hungarian traditions and strong environmental concerns, is an ideal case study for understanding consumer perceptions of edible insects and increasing their acceptance as an alternative protein source. A survey conducted in Slovenian and English with 537 participants examined existing perceptions and acceptance of edible insects as food and livestock feed. Findings show moderate interest in insects, particularly in non-visible, integrated forms, despite most participants not having tried whole insects. Young, educated individuals and those residing in rural areas have tried insects more often than other sociodemographic groups. Men showed more interest in entomophagy compared to women. Crickets, grasshoppers, and locusts were most acceptable, while cockroaches were least favored. Economic factors are crucial, with a preference for insect-based products priced similarly to conventional foods. The majority also support using insects as livestock feed. These results can aid policymakers at regional and national levels, help businesses market these products, and contribute to the literature on consumer responses in different European regions regarding edible insects as a sustainable food source.
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This study investigates consumer preference and acceptance of three meat alternatives-plant-based, lab-grown, and insect-based-as sustainable choices to meet the demands of a growing population and evolving food systems. Insights were gathered from European consumers regarding their perceptions and consumption patterns using a mixed-methods approach. The approach employed a questionnaire followed by focus group discussions conducted in Slovenia and the UK to understand the motivations and barriers behind their responses. The UK and Slovenia were chosen as they provided the highest response rates to the questionnaire and they have differing legislation. The results show that plant-based alternatives are the most familiar and accepted option, while lab-grown meat and insect-based products are less familiar and have lower acceptance rates. Moreover, they show that although sustainability factors are important to consumers, they are not their only concern; health and nutrition are the primary motivators for choosing meat alternatives. These are followed closely by sensory appeal, pricing, and a preference for natural, minimally processed options. Based on insights from the focus groups, strategies to overcome the barriers to the acceptance of meat alternatives should include targeted product categorisation and placement, educational campaigns, effective use of media, and greater transparency in product information.
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The formation of volatile organic compounds (VOCs) in dry-cured ham is a result of different biochemical and enzymatic processes. Moreover, accurately quantifying these VOCs is challenging since ham is a complex matrix, which contains compounds from various chemical families and a wide range of volatilities of different molecular masses. In this study, we systematically optimized and validated an analytical method for quantifying VOCs in dry-cured ham using headspace solid phase microextraction (HS-SPME) coupled with gas chromatography-mass spectrometry (GC-MS). Optimal SPME conditions were determined through both an experimental procedure (one-factor-at-a-time) and response surface methodology (RSM), revealing that a 60-min equilibration at 70°C, a 60-min extraction at the same temperature, and a 4-min desorption time at 250°C provided the most favorable results. To enhance quantitation, twelve multiple internal standards (ISTDs) were employed to address and improve the quantitation of the 12 VOCs. Method validation covered aspects of linearity, limits of detection (LOD: 0.03-1.13 mg kg-1), limits of quantitation (LOQ: 0.09-3.41 mg kg-1), and working ranges (0.01-19.1 mg kg-1). The practical application of this optimized method was demonstrated by analyzing dry-cured ham samples (n = 4), sourced from the Slovenian market. The initial statistical evaluation indicates that different types of dry-cured hams can be differentiated (with an 83.1% of accuracy) according to their aromatic profile. However, a larger sample size would be required to provide a more comprehensive assessment.
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Following the tradition of the 16th International Conference on Chemistry and the Environment (ICCE) in Oslo, Norway (2017), and the subsequent 17th ICCE in Thessaloniki, Greece (2019), a follow-up session on higher education in environmental science was organized at the 18th ICCE in Venice, Italy (June 2023). The aim of the session was to stimulate the exchange of experiences and knowledge on graduate and post-graduate level educational programmes, including their development, prioritization, and implementation. The session discussed the integration of practical training activities, which included the integration of environmental chemistry in various bachelor's and master's programmes. The aim was to demonstrate the versatility of environmental chemistry as an interdisciplinary scientific discipline that allows the development of essential green skills for developing sustainable strategies for the environmental experts of tomorrow. Furthermore, during the session, a survey was conducted among the conference participants to collect attitudes and reflections from the audience on the education of environmental chemistry (and related fields).
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Given the global decline in adherence to the Mediterranean Diet (MD), even within its native region, it is key to identify the factors influencing this trend to mitigate the negative health outcomes associated with westernized diets. To this end, 4025 individuals (49.6% women, 42.6 ± 14.2 y/o) from Greece, Italy, Morocco, Slovenia, and Tunisia remotely completed a series of measures assessing motives, attitudes, and psychosocial factors related to MD adherence, which was evaluated using the MEDAS questionnaire. The results suggested medium-to-low adherence across all countries, with the highest adherence in Italy and Morocco and the lowest in Slovenia. Structural equation modeling revealed that positive attitudes toward the healthiness of food were the strongest predictors of adherence, whereas picky eating was a significant negative predictor in all countries except Greece. Adherence to the MD was positively influenced by health motivations in Morocco and weight control in Slovenia and Greece, while sensory appeal negatively influenced adherence in Italy. Additionally, price and convenience were significant barriers in Tunisia and Greece, whereas a preference for local and seasonal foods promoted adherence in Morocco and Greece. Overall, our findings underscore the need for country-specific interventions and policies that address distinct local factors and motivations to ease favorable shifts in dietary patterns toward MD principles.
Assuntos
Dieta Mediterrânea , Humanos , Dieta Mediterrânea/estatística & dados numéricos , Dieta Mediterrânea/psicologia , Feminino , Masculino , Adulto , Marrocos , Itália , Pessoa de Meia-Idade , Grécia , Tunísia , Eslovênia , Motivação , Inquéritos e Questionários , Comportamento Alimentar/psicologia , Cooperação do Paciente/estatística & dados numéricosRESUMO
A combination of molecular and stable isotope analyses was used to trace and identify the sources of polycyclic aromatic hydrocarbons (PAH) in sediments of Lake Bled (NW Slovenia). Sediment samples were taken from two locations with contrasting depositional regimes: Zaka Bay, with permanently oxic bottom and station D, where anoxic conditions prevail throughout the year. The concentrations of PAH in surface sediments at the two locations were comparable and higher than in previous studies, reaching 4230 and 4380 ng g(-1), respectively. It was found that retene (Re) and perylene (Per) are both mainly of natural origin in Zaka Bay while, at station D, the value of δ(13)C determined at a depth of 12-14 cm in the 1950s indicated that Re was of pyrolytic origin. The distribution of δ(13)C values of other individual PAH showed that PAH input to lake sediments was of pyrolytic origin, likely dominated by coal and later in 1950s also by wood burning. PAH from vehicular emissions could also contribute to the overall isotope signatures at the depth of 12-14 cm at station D and Zaka Bay corresponding to the period 1953-1961.
Assuntos
Monitoramento Ambiental , Sedimentos Geológicos/química , Marcação por Isótopo , Lagos/química , Hidrocarbonetos Policíclicos Aromáticos/análise , Carbono/análise , Isótopos de Carbono , Geografia , EslovêniaRESUMO
In this study, seasonal changes of mercury (Hg) species in the highly variable estuary of Soca/Isonzo River (northern Adriatic Sea) were investigated. Samplings were performed on a seasonal basis (September 2009, May, August and October 2010) and Hg species (total Hg, methylmercury (MeHg), dissolved gaseous Hg (DGM)) in waters, sediments and pore waters were determined. In addition, a range of ancillary parameters were measured (salinity, nutrients, organic carbon (OC), nitrogen species). Hg values were interpreted using these parameters and hydrological conditions (river flow, wave height) around the time of sampling. There were no significant changes in Hg load from river to the gulf, compared to previous studies. The load was temporarily higher in May 2010 due to higher river flow. Wave height, through changing hydrostatic pressure, was most likely to cause resuspension of already deposited Hg from the bottom (August 2010). The estuary is a net source of DGM to the atmosphere as suggested by DGM profiles, with salinity, redox potential and organic matter as the most probable controls over its production. MeHg is produced in situ in sediment or in water column, rather than transported by river, as indicated by its correlation with OC of the marine origin. Calculated fluxes for THg and MeHg showed sediment as a source for both the water column. In pore waters, OC in part affects partitioning of both THg and MeHg; however other factors (e.g. sulphide and/or oxyhydroxides precipitation and dissolution) are also probably important.
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Monitoramento Ambiental/estatística & dados numéricos , Estuários , Mercúrio/química , Compostos de Metilmercúrio/metabolismo , Estações do Ano , Poluentes Químicos da Água/química , Carbono/análise , Monitoramento Ambiental/métodos , Mar Mediterrâneo , Mercúrio/análise , Nitrogênio/análise , Salinidade , Eslovênia , Espectrometria de Fluorescência , Movimentos da Água , Poluentes Químicos da Água/análiseRESUMO
While the demand for Spirulina dietary supplements continues to grow, product inspection in terms of authenticity and safety remains limited. This study used the stable isotope ratios of light elements (C, N, S, H, and O) and the elemental composition to characterize Spirulina dietary supplements available on the Slovenian market. Forty-six samples were labelled as originating from the EU (1), non-EU (6), Hawaii (2), Italy (2), Japan (1), Portugal (2), Taiwan (3), India (4), and China (16), and nine products were without a declared origin. Stable isotope ratio median values were -23.9‱ (-26.0 to -21.8‱) for δ13C, 4.80‱ (1.30-8.02‱) for δ15N, 11.0‱ (6.79-12.7‱) for δ34S, -173‱ (- 190 to -158‱) for δ2H, and 17.2‱ (15.8-18.8‱) for δ18O. Multivariate statistical analyses achieved a reliable differentiation of Hawaiian, Italian, and Portuguese (100%) samples and a good separation of Chinese samples, while the separation of Indian and Taiwanese samples was less successful, but still notable. The study showed that differences in isotopic and elemental composition are indicative of sample origins, cultivation and processing methods, and environmental conditions such that, when combined, they provide a promising tool for determining the authenticity of Spirulina products.
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Knowledge about the interactions between dietary and biomedical factors is scattered throughout uncountable research articles in an unstructured form (e.g., text, images, etc.) and requires automatic structuring so that it can be provided to medical professionals in a suitable format. Various biomedical knowledge graphs exist, however, they require further extension with relations between food and biomedical entities. In this study, we evaluate the performance of three state-of-the-art relation-mining pipelines (FooDis, FoodChem and ChemDis) which extract relations between food, chemical and disease entities from textual data. We perform two case studies, where relations were automatically extracted by the pipelines and validated by domain experts. The results show that the pipelines can extract relations with an average precision around 70%, making new discoveries available to domain experts with reduced human effort, since the domain experts should only evaluate the results, instead of finding, and reading all new scientific papers.
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Mineração de Dados , Reconhecimento Automatizado de Padrão , Humanos , Mineração de Dados/métodos , Idioma , Processamento de Linguagem NaturalRESUMO
As population growth and climate change add to the problem of water scarcity in many regions, the argument for using treated wastewater for irrigation is becoming increasingly compelling, which makes understanding the risks associated with the uptake of harmful chemicals by crops crucial. In this study, the uptake of 14 chemicals of emerging concern (CECs) and 27 potentially toxic elements (PTEs) was studied in tomatoes grown in soil-less (hydroponically) and soil (lysimeters) media irrigated with potable and treated wastewater using LC-MS/MS and ICP-MS. Bisphenol S, 2,4 bisphenol F, and naproxen were detected in fruits irrigated with spiked potable water and wastewater under both conditions, with BPS having the highest concentration (0.034-0.134 µg kg-1 f. w.). The levels of all three compounds were statistically more significant in tomatoes grown hydroponically (Assuntos
Água Potável
, Solanum lycopersicum
, Cromatografia Líquida
, Espectrometria de Massas em Tandem
, Águas Residuárias