1.
IUCrdata
; 8(Pt 8): x230657, 2023 Aug.
Artigo
em Inglês
| MEDLINE
| ID: mdl-37693785
RESUMO
The title cluster compound, [Mo4(η5-C5H4Me)4(µ3-Se)4], was synthesized from the reaction of [Mo(η5-C5H4Me)(CO)3]2 with grey selenium in refluxing xylene solution under a nitro-gen atmosphere. The complete cluster is generated by a crystallographic twofold axis and contains an Mo4Se4 cubane-like core surrounded by four η5-methylcyclo-pentadienyl ligands. In the core, the four molybdenum atoms are connected to each other to form a tetra-hedron, with a selenium atom capping each face. The Mo-Mo bond lengths vary from 2.9857â (5) to 3.0083â (3)â Å and the Mo-Se separations range from 2.4633â (4) to 2.4693â (5)â Å.