Environmental and ecological risk assessment of municipal sewage sludge management using a sustainable solar drying system.

Providing a cost-effective and suitable way for sewage sludge refinement with the purpose of reducing environmental impacts or reutilization of sewage sludge can be an important issue for researchers. This study is inclined at bringing an economical and sustainable solution to sludge management in a municipal wastewater treatment plant. Three types of sludges were collected for the experiments: raw sludge was collected during winter (R.S.), digested sludge was collected during winter (D.S.1), and digested sludge was collected during summer time (D.S.2). This study proposes replacing mechanical drying by a solar drying system. Experimental analysis was carried out to determine the total solids (TS), volatile solids (VS), heavy metals concentration, and pollution index (index of geo accumulation, contamination factor, ecological risk factor). The solar drying system was demonstrated to be very efficient with the three samples achieving a dry solid content of 96.96% for R.S., 96.75% for D.S.1, and 93.60% for D.S.2. after solar drying. While pollution index calculations showed that all three sludges present a low potential ecological risk.

KOH modified Thevetia peruviana shell activated carbon for sorption of dimethoate from aqueous solution.

Modified Thevetia peruviana shell activated carbon for sorption of dimethoate from aqueous solution derived with potassium hydroxide (KOH) was studied at different concentrations for its potential application in water treatment. The batch sorption was investigated using dimethoate solution of 10-100 mg/L concentrations. Proximate analysis was determined and changes on the surfaces and structure of the TPS were characterized after chemical activation with KOH using XRD, FTIR, SEM-EDAX, pHpzc, BET. The quantum chemical calculation for dimethoate yielded molecule associated energies of -9.8421 (HOMO) and -2.3879 (LUMO) and a total energy of -53,376.2. The kinetic of the sorption was modeled which indicated the sorption equilibrium time as 90 min and pseudo-first order kinetics model showing R2 = 0.994 provided a better description of the process. Analysis of sorption equilibrium revealed that the data fitted well to Freundlich sorption isotherm model (R2 = 0.966), indicating multi-layer sorption of dimethoate on the surface of sorbent. The sorption of dimethoate onto KOHTPS shows 92.60% removal efficiency.