Retrieving the real refractive index of mono- and polydisperse colloids from reflectance near the critical angle.

We investigate the accuracy in retrieving the real refractive index of submicron aerosol particles, at a visible wavelength, from near critical angle reflectance measurements of a dilute suspension of the aerosol. A coherent scattering model (CSM) is used to model the coherent reflectance from the colloidal suspension. We use an extension of the model for polydisperse particles to properly account for the modified size distribution close to the incident medium to colloid interface. We perform a rigorous sensitivity analysis, for both the monodisperse and polydisperse models, to determine how experimental uncertainties propagate into uncertainty in the retrieval of real refractive index. The effect of non-spherical scattering was included in the sensitivity analysis by using T-matrix methods. Experimental reflectance data, at a wavelength of 635 nm, were obtained for monodisperse spherical latex particles, a polydisperse sand sample and a polydisperse volcanic ash sample. We show that the retrieved real refractive index for these particles is consistent with values obtained using other techniques.

Estimation of a lidar's overlap function and its calibration by nonlinear regression.

The overlap function of a Raman channel for a lidar system is retrieved by nonlinear regression using an analytic description of the optical system and a simple model for the extinction profile, constrained by aerosol optical thickness. Considering simulated data, the scheme is successful even where the aerosol profile deviates significantly from the simple model assumed. Application to real data is found to reduce by a factor of 1.4-2.0 the root-mean-square difference between the attenuated backscatter coefficient as measured by the calibrated instrument and a commercial instrument.

Composition of smoke generated by landing aircraft.

A combination of techniques has been used to examine the composition of smoke generated by landing aircraft. A sample of dust from the undercarriage from several commercial airliners was examined with SEM/EDX (Scanning Electron Microscope/Energy Dispersive X-ray) to determine its elemental composition and also with an aerosizer/aerodisperser in order to measure the particle size spectrum. The observed size spectrum was bimodal with equal numbers of particles at peaks of aerodynamic diameter ∼10 µm and ∼50 µm. The EDX analysis suggested that the former peak is carbonaceous, while the latter consists of elements typical of an asphalt concrete runway. In the field, a scanning Lidar, in combination with optical and condensation particle counters, was deployed to obtain limits to the number concentration and size of such particles. Most of the (strong) Lidar signal probably arose from the coarser 50 µm aerosol, while respirable aerosol was too sparse to be detected by the optical particle counters.