RESUMO
Single-atom and nanocluster catalysts presenting potent catalytic activity and excellent stability are used in high-temperature applications such as in structural composites, electrical devices, and catalytic chemical reactions. Recently, more attention has been drawn to application of these materials in clean fuel processing based on oxidation in terms of recovery and purification. The most popular media for catalytic oxidation reactions include gas phases, pure organic liquid phases, and aqueous solutions. It has been proven from the literature that catalysts are frequently selected as the finest in regulating organic wastewater, solar energy utilization, and environmental treatment applications in most catalytic oxidation of methane vis-à-vis photons and in environmental treatment applications. Single-atom and nanocluster catalysts have been engineered and applied in catalytic oxidations considering metal-support interactions and mechanisms facilitating catalytic deactivation. In this review, the present improvements on engineering single-atom and nano-catalysts are discussed. In detail, we summarize structure modification strategies, catalytic mechanisms, methods of synthesis, and application of single-atom and nano-catalysts for partial oxidation of methane (POM). We also present the catalytic performance of various atoms in the POM reaction. Full knowledge of the use of remarkable POM vis-à-vis the excellent structure is revealed. Based on the review conducted on single-atom and nanoclustered catalysts, we conclude their viability for POM reactions; however, the catalyst design must be carefully considered not only for isolating the individual influences from the active metal and support but also for incorporating the interactions of these components.
RESUMO
Preceramic polymers, for instance, are used in a variety of chemical processing industries and applications. In this contribution, we report on the catalytic oxidation reactions generated using preceramic polymer catalyst supports. Also, we report the full knowledge of the use of the remarkable catalytic oxidation, and the excellent structures of these preceramic polymer catalyst supports are revealed. This finding, on the other hand, focuses on the functionality and efficacy of future applications of catalytic oxidation of preceramic polymer nanocrystals for energy and environmental treatment. The aim is to design future implementations that can address potential environmental impacts associated with fuel production, particularly in downstream petroleum industry processes. As a result, these materials are being considered as viable candidates for environmentally friendly applications such as refined fuel production and related environmental treatment.
RESUMO
In this work, the formation of two- and three-component supramolecular systems based on cone, partial cone, 1,3-alternate stereoisomers of heteroditopic "hosts": p-tert-butylthiacalix[4]arene containing 4-amidopyridine fragments with silver(I) cations and dicarboxylic acids in liquid and solid phases were studied by UV spectroscopy, dynamic light scattering, and atomic force microscopy methods. It has been shown that these macrocycles are coreceptors, capable of simultaneously binding silver(I) cations, dicarboxylic acids (oxalic, malonic, succinic, maleic, fumaric acids), and hydroxyl acids (glycol, tartaric acids). For the first time, by the dynamic light scattering method, it has been shown that the conformation of p-tert-butyl thiacalix[4]arenes significantly affects the type of three-component system formed: cone is characterized by the formation of cascade systems; for partial cone, intermediate systems; and for the 1,3-alternate stereoisomers, three types of three-component systems (cascade, intermediate, and commutative) were observed.