Sustainable remediation of pesticide pollutants using covalent organic framework - A review on material properties, synthesis methods and application.

Covalent organic frameworks (COF) have emerged as a potential class of materials for a variety of applications in a wide number of sectors including power storage, environmental services, and biological applications due to their ordered and controllable porosity, large surface area, customizable structure, remarkable stability, and diverse electrical characteristics. COF have received a lot of attention in recent years in the field of environmental remediation, It also find its way to eliminate the emerging pollutant from the environment notably pesticide from polluted water. This review more concentrated on the application of COF in pesticide removal by modifying COF structure, COF synthesis and material properties. To increase the adsorption ability and selectivity of the material towards certain pesticides removal, the synthesis of COF involves organic linkers with various functional groups such as amine, carboxylic acid groups etc. The COF have a high degree of stability and endurance make them suitable for intermittent usage in water treatment applications. This review manifests the novel progress where modified COFs employed in a prominent manner to remove pesticides from polluted water. Some examples of COF application in the eradication of pesticides are triformyl phenylene framework functionalized with amine groups has capacity to remove up to 50 mg/l of Organophosphorus - chlorpyrifos. COF modified to improve their photocatalytic capacity to breakdown the pesticide under visible light irradiation. COF tetraphenyl ethylene linked with carboxylic acid group shows efficient photocatalytic degradation of 90% of organochlorine insecticide endosulfan when subjected to visible light. Atrazine and imidacloprid are reduced from 100 ppm to 1 ppm in aqueous solutions by COF based on high adsorption capacity. In addition, the strategies, technique, synthesis and functional group modification design of COF are discussed.

Biodegradation of chlorpyrifos pollution from contaminated environment - A review on operating variables and mechanism.

Chlorpyrifos (CPF) is a highly toxic phosphate-rich organic pesticide (OP), identified as an emerging contaminant and used extensively in agricultural production. CPF persistence in the environment and its potential health hazards has become increasingly concerning worldwide in recent years due to exponential rise in food demand. Biodegradation of chlorpyrifos by microbial cultures is a promising approach to reclaiming contaminated soil and aquatic environments. The purpose of this review is to summarize the current understanding of microbiological aspects of xenobiotic chlorpyrifos biodegradation, including microbial diversity, metabolic pathways, and factors that modulate it. In both aerobic and anaerobic environments, CPF is biochemically broken down by a broad spectrum of bacteria and fungi. Hydrolysis, dehalogenation, and oxidation of chlorpyrifos are all enzymatic reactions that lead to its degradation. Biodegradation rate and efficiency are strongly influenced by parametric variables such as co-substrates abundance, pH, temperature, and initial chlorpyrifos concentration. The review provides evidence that microbial biodegradation is a viable method for remediating chlorpyrifos-contaminated sites in a sustainable and safe manner.

Solving the fouling mechanisms in composite membranes for water purification: An advance approach.

With the increasing population worldwide more wastewater is created by human activities and discharged into the waterbodies. This is causing the contamination of aquatic bodies, thus disturbing the marine ecosystems. The rising population is also posing a challenge to meet the demands of fresh drinking water in the water-scarce regions of the world, where drinking water is made available to people by desalination process. The fouling of composite membranes remains a major challenge in water desalination. In this innovative study, we present a novel probabilistic approach to analyse and anticipate the predominant fouling mechanisms in the filtration process. Our establishment of a robust theoretical framework hinges upon the utilization of both the geometric law and the Hermia model, elucidating the concept of resistance in series (RIS). By manipulating the transmembrane pressure, we demonstrate effective management of permeate flux rate and overall product quality. Our investigations reveal a decrease in permeate flux in three distinct phases over time, with the final stage marked by a significant reduction due to the accumulation of a denser cake layer. Additionally, an increase in transmembrane pressure leads to a correlative rise in permeate flux, while also exerting negative effects such as membrane ruptures. Our study highlights the minimal immediate impact of the intermediate blocking mechanism (n = 1) on permeate flux, necessitating continuous monitoring for potential long-term effects. Additionally, we note a reduced membrane selectivity across all three fouling types (n = 0, n = 1.5, n = 2). Ultimately, our findings indicate that the membrane undergoes complete fouling with a probability of P = 0.9 in the presence of all three fouling mechanisms. This situation renders the membrane unable to produce water at its previous flow rate, resulting in a significant reduction in the desalination plant's productivity. I have demonstrated that higher pressure values notably correlate with increased permeate flux across all four membrane types. This correlation highlights the significant role of TMP in enhancing the production rate of purified water or desired substances through membrane filtration systems. Our innovative approach opens new perspectives for water desalination management and optimization, providing crucial insights into fouling mechanisms and proposing potential strategies to address associated challenges.

Enhanced mitigation of acidic and basic dyes by ZnO based nano-photocatalysis: current applications and future perspectives.

Dye wastewater possess immense toxicity with carcinogenic properties and they persist in environment owing to their stability and resistance to chemical and photochemical changes. The bio degradability of dye-contaminated wastewater is low due to its complex molecular structure. Nano-photocatalysts based on zinc oxide are reported as one of the effective metal oxides for dye remediation due to their photostability, enhanced UV and visible absorption capabilities in an affordable manner. An electron-hole pair forms when electrons in the valence band of ZnO nano-photocatalyst transfer into the conduction band by absorbing UV light. The review article presents a detailed review on ZnO applications for treating acidic and basic dyes along with the dye degradation performance based on operating conditions and photocatalytic kinetic models. Several acidic and basic dyes have been shown to degrade efficiently using ZnO and its nanocomposites. Higher removal percentages for crystal violet was reported at pH 12 by ZnO/Graphene oxide catalyst under 400 nm UV light, whereas acidic dye Rhodamine B at a pH of 5.8 was degraded to 100% by pristine ZnO. The mechanism of action of ZnO nanocatalysts in degrading the dye contamination are reported and the research gaps to make these agents in environmental remediation on real time operations are discussed.

Environmental remediation of selenium using surface modified carbon nano tubes - Characterization, influence of variables, equilibrium and kinetic analysis.

Selenium is targeted as a priority pollutant to be removed due to its high toxicity level and lethal effects. In this research, a novel nano sorbent was fabricated using ionic liquid on multiwalled carbon nanotubes (IL-MCNT) and employed for Selenium remediation from aqueous media. Besides solution pH, nanocomposite dosage, the initial selenium concentration, temperature and sorption time were also examined as operating variables. At optimal pH 2.0, 96% of the selenium was removed with maximum efficiency with 100 mg/L of IL-MCNT at 308 K, 45 min of contact time, and 110 g of IL-MCNT dosage. From kinetic studies, it appears that the Langmuir isotherm fits the observed data (R2 > 0.9813), supporting the hypothesis that monolayer attachment occurs. The Langmuir isotherm parameters are evaluated as qm = 125 mg/g and KL = 0.172 L/mg. As a result of testing several kinetic models, the pseudo-second-order model was the most suitable for experimental data (R2 > 0.9746). Scanning Electron Microscopy images, FTIR spectra, and thermogravimetric study were used to examine the synthesized nanomaterial.

Bio-fabrication of porous magnetic Chitosan/Fe3O4 nanocomposite using Azolla pinnata for removal of chromium - Parametric effects, surface characterization and kinetics.

In this research, a novel porous nanocomposite, namely Chitosan-iron-oxide @ Azolla pinnata nanocomposite, has been synthesized by co-precipitation and hydrothermal method. The effect of process parameter on adsorption process was investigated. Batch removal of chromium (Cr) was optimized with respect to solution pH, batch stirring time, sorbent dose, initial chromium concentration and temperature. The maximum removal efficiency was found to be 98.58%. The Fourier transform infrared (FTIR) spectroscopy and scanning electron microscope (SEM) analysis of the nano composite confirmed the presence of characteristic functional groups and porous structure of synthesized nanocomposite. The adsorption data fitted well with Langmuir adsorption isotherm (R2 = 0.996) confirming mono layer sorption and the maximum uptake was found to be 294.12 mg/g. The adsorption was found to follow pseudo second order model (R2 = 0.997). Thermodynamic studies revealed that adsorption is endothermic and spontaneous. Reusability studies have confirmed that removal efficiency attained was 85% after completion of five adsorption-desorption cycles. Electrostatic attraction, ion exchange, coordination bonding and reduction are the major mechanisms responsible for removal of chromium. Surface modification of Azolla pinnata with chitosan and iron oxide improved the ability of Azolla in the adsorption of chromium from aqueous media. The combined effects of facile synthesis, improved adsorption features and easier magnetic separation promotes Chitosan-iron-oxide @ Azolla pinnata nanocomposite as a novel adsorbent.

Physico-chemical and biological remediation techniques for the elimination of endocrine-disrupting hazardous chemicals.

Due to their widespread occurrence and detrimental effects on human health and the environment, endocrine-disrupting hazardous chemicals (EDHCs) have become a significant concern. Therefore, numerous physicochemical and biological remediation techniques have been developed to eliminate EDHCs from various environmental matrices. This review paper aims to provide a comprehensive overview of the state-of-the-art remediation techniques for eliminating EDHCs. The physicochemical methods include adsorption, membrane filtration, photocatalysis, and advanced oxidation processes. The biological methods include biodegradation, phytoremediation, and microbial fuel cells. Each technique's effectiveness, advantages, limitations, and factors affecting their performance are discussed. The review also highlights recent developments and future perspectives in EDHCs remediation. This review provides valuable insights into selecting and optimizing remediation techniques for EDHCs in different environmental matrices.

PAHs remediation from hazardous waste landfill leachate using fenton, photo - fenton and electro - fenton oxidation processes - performance evaluation under optimized conditions using RSM and ANN.

Polycyclic aromatic hydrocharbons (PAHs) are a class of highly toxic pollutants that are highly detrimental to the ecosystem. Landfill leechate emanated from municipal solid waste are reported to constitute significant PAHs. In the present investigation, three Fenton proceses, namely conventional Fenton, photo-fenton and electro-fenton methods have been employed to treat landfill leehcate for removing PAHs from a waste dumpig yard. Response surface methodology (RSM) and artificial neural network (ANN) methodologies were adopted to optimize and validate the conditions for optimum oxidative removal of COD and PAHs. The statistical analysis results showed that all independent variables chosen in the study are reported to have significant influence of the removal effects with P-values <0.05. Sensitivity analysis by the developed ANN model showed that the pH had the highest significance of 1.89 in PAH removal when compared to the other parameters. However for COD removal, H2O2 had the highest relative importance of 1.15, followed by Fe2+ and pH. Under optimal treatment conditions, the photo-fenton and electro-fenton processes showed better removal of COD and PAH compared to the Fenton process. The photo-fenton and electro-fenton treatment processes removed 85.32% and 74.64% of COD and 93.25% and 81.65% of PAHs, respectively. Also the investigations revelaed the presence of 16 distinct PAH compunds and the removal percentage of each of these PAHs are also reported. The PAH treatment research studies are generally limited to the assay of removal of PAH and COD levels. In the present investigation, in addition to the treatment of landfill leachate, particle size distribution analysis and elemental characterization of the resultant iron sludge by FESEM and EDX are reported. It was revealed that elemental oxygen is present in highest percentage, followed by iron, sulphur, sodium, chlorine, carbon and potassium. However, iron percentage can be reduced by treating the Fenton-treated sample with NaOH.

Recent trends in MXene-based material for biomedical applications.

MXene is a magical class of 2D nanomaterials and emerging in many applications in diverse fields. Due to the multiple advantageous characteristics of its fundamental components, such as structural, physicochemical, optical, and occasionally even biological characteristics. However, it is limited in the biomedical industry due to poor physiological stability, decomposition rate, and lack of controlled and sustained drug release. These limitations can be overcome when MXene forms composites with other 2D materials. The efficiency of pure MXene in biomedicine is inferior to that of MXene-based composites. The availability of functionality on the exterior part of MXene has a key role in the modification of their surface and their characteristics. This review provides an extensive discussion on the synthesizing of MXene and the role of the surface functionalities on the efficiency of MXene. In addition, a detailed discussion of the biomedical applications of MXene, including antibacterial activity, regenerative medicine, CT scan capability, drug delivery, diagnostics, MRI and biosensing capability. Furthermore, an outline of the future problems and challenges of MXene-based materials for biomedical applications was narrated. Thus, these salient features showcase the potential of MXene-based material and will be a breakthrough in biomedical applications in the near future.

Emerging waste-to-wealth applications of fly ash for environmental remediation: A review.

The considerable increase in world energy consumption owing to rising global population, intercontinental transportation and industrialization has posed numerous environmental concerns. Particularly, in order to meet the required electricity supply, thermal power plants for electricity generation are widely used in many countries. However, an annually excessive quantity of waste fly ash up to 1 billion tones was globally discarded from the combustion of various carbon-containing feedstocks in thermoelectricity plants. About half of the industrially generated fly ash is dumped into landfills and hence causing soil and water contamination. Nonetheless, fly ash still contains many valuable components and possesses outstanding physicochemical properties. Utilizing waste fly ash for producing value-added products has gained significant interests. Therefore, in this work, we reviewed the current implementation of fly ash-derived materials, namely, zeolite and geopolymer as efficient adsorbents for the environmental treatment of flue gas and polluted water. Additionally, the usage of fly ash as a catalyst support for the photodegradation of organic pollutants and reforming processes for the corresponding wastewater remediation and H2 energy generation is thoroughly covered. In comparison with conventional carbon-based adsorbents, fly ash-derived geopolymer and zeolite materials reportedly exhibited greater heavy metal ions removal and reached the maximum adsorption capacity of about 150 mg g-1. As a support for biogas reforming process, fly ash could enhance the activity of Ni catalyst with 96% and 97% of CO2 and CH4 conversions, respectively.

Microbial electro deionization for waste water treatment - A critical review on methods, applications and mechanism.

Electro deionization using microbial communities has been proven as a competent method for desalination and abatement of water pollution by removing ionic chemicals from the target waters. Microbial Desalination Cell (MDC) facilitates microbial deionization which can either support or be a substitute for the conventional desalination methods. Generation of electricity is accomplished by the bio electrochemical oxidation of organic compounds present as contaminants in wastewater which in turn attribute to the migration of ions in MDC system. The present review aims to elucidate the theory, principles and the application of microbial desalination cell and microbial fuel cell (MFC) in treatment of saline and wastewaters. Air cathode MDC and stacked MDC for purification of saline water are found to give promising results. Air pump assisted microbial desalination cell reported 150.39 ppm h-1 of salt removal with an operational time period of 80 h and showed consistent results. Hence the air cathode assisted MDC showed dominant capacity of salt removal compared to stacked MDC. Also, three major types of microbial fuel cell, namely photosynthetic biofilm MFC, constructive wetland MFC and ceramic membrane supported MFC are reviewed for their potentials in wastewater treatment by deionization method and electricity generation. Complete (100%) removal of chemical oxygen demand was reported by photosynthetic microbial fuel cell operated for 16 days having 435.8 Ω of external resistance. When constructive wetland microbial fuel cell was operated for 10 days with 1000 ohms of external resistance, it exhibited complete (100%) removal of chemical oxygen demand from the wastewater. About 92% of chemical oxygen demand removal was demonstrated by ceramic membrane supported microbial fuel. Compared to ceramic membrane microbial fuel cell, photosynthetic and constructive wetland microbial fuel cell displayed better performance in terms of pollutant removal capacity and economical factor. Ability of the electrogenic species, namely Geobacter, Shewanella, Clostridium and Bacillus and the photosynthetic species, namely Chorella Vulgaris Rhodopsuedomonas, and Scenedesmus abundans in microbial deionization methods and their performance levels reported by several researchers are presented.

Enhanced remediation of lead (II) and cadmium (II) ions from aqueous media using porous magnetic nanocomposites - A comprehensive review on applications and mechanism.

Lead and Cadmium, identified as toxic heavy metals, cause significant imbalance in the eco-system due to their tendency to bioaccumulate. Remediation of heavy metals by conventional adsorptive materials suffer demerits related to low efficiency or removal. Among the variety of adsorbent materials used in the adsorption process, metal oxides- and graphene oxide magnetic nanocomposites have gained a considerable attention. The use of nanomaterials may help to reduce this contamination, but after use, they are difficult to remove from water. An added magnetic property to nanomaterials facilitates their retrieval after use. The magnetic properties of these hybrid magnetic nanocomposites, coupled with unique characteristics of organic and inorganic elements, have found extensive application in water treatment technology. Detailed discussion on functionalisation of magnetic nanocomposites and the enhanced performance are presented. Magnetic graphene oxide-covalently functionalized-tryptophan was reported to have the highest adsorption capacity of 766.1 mg/g for remediation of lead (II) ions and graphene oxide exhibited the highest adsorption capacity of 530 mg/g for Cd (II) ions. The adsorption mechanisms for heavy metal ions on the surface of novel adsorbents, particularly lead and cadmium, using magnetic nanocomposites have been explained with reference to the isotherm models studied. The future scope of research in this area of research is proposed.

Environmentally benign Prosopis juliflora extract for corrosion protection by sorption - Gravimetric, mechanistic and thermodynamic studies.

Environmentally benign plant extract compounds have gained significant attention in the corrosion prevention applications due to their biodegradability and eco-friendliness. The adsorptive corrosion control action of Prosopis juliflora plant extract was investigated using differential mass change experiments and the mechanism was validated using Tafel and Nyquist plots. The effect of green corrosion inhibitor concentration (0-800 ppm) on corrosion rate at different solution temperatures (305.15, 310.15 and 315.15 K) in 1 M HCl was studied. The corrosion inhibitor exhibited monolayer surface coverage and confirmed by Langmuir isotherm (R2 > 0.970). The negative values of Gibbs free energy (<20 kJ/mol) proved the electrostatic interaction between the inhibitor and metal surface. The enhanced energy barrier for the corrosion process was confirmed by changes in Ea in the presence of biomass-based inhibitor on the mild steel surface. Electrochemical impedance study proved that the double layer capacitance (Cdl) decreased and the resistance increased with increase in corrosion inhibitor concentration. The surface modifications on the metal were observed using scanning electroscope imaging. ATR studies were conducted for functional group identification of the corrosion inhibitor.

Thermochemical conversion of municipal solid waste into energy and hydrogen: a review.

The rising global population is inducing a fast increase in the amount of municipal waste and, in turn, issues of rising cost and environmental pollution. Therefore, alternative treatments such as waste-to-energy should be developed in the context of the circular economy. Here, we review the conversion of municipal solid waste into energy using thermochemical methods such as gasification, combustion, pyrolysis and torrefaction. Energy yield depends on operating conditions and feedstock composition. For instance, torrefaction of municipal waste at 200 °C generates a heating value of 33.01 MJ/kg, while the co-pyrolysis of cereals and peanut waste yields a heating value of 31.44 MJ/kg at 540 °C. Gasification at 800 °C shows higher carbon conversion for plastics, of 94.48%, than for waste wood and grass pellets, of 70-75%. Integrating two or more thermochemical treatments is actually gaining high momentum due to higher energy yield. We also review reforming catalysts to enhance dihydrogen production, such as nickel on support materials such as CaTiO3, SrTiO3, BaTiO3, Al2O3, TiO3, MgO, ZrO2. Techno-economic analysis, sensitivity analysis and life cycle assessment are discussed.

Remediation of carcinogenic PAHs from landfill leachate by Electro-Fenton process - Optimization and modeling.

PAHs is the group of emerging micro-pollutants present in most environmental matrices that has the tendency to bioaccumulate and cause carcinogenic effects to human health. The present research involved the quantification and treatment of leachate produced from secured landfill, to eliminate the PAHS. Electro-Fenton process, a class of advanced oxidation process, is adopted to degrade the PAHs using titanium electrodes as both anode and cathode. Artificial intelligence based statistical tool "Central Composite Design" a module of JMP -19 software was used to design the experiments and optimize the critical parameters involved in the research. It was observed that the value of P is significant (P < 0.05) for all the independent variables evidencing the significant correlation between experimental values and predicted values of the software. The value of R2 obtained was 0.96 and 0.97 for COD and PAHs respectively. The maximum removal efficiency of COD and PAH was found to be 84.24% and 90.78% respectively. The optimized conditions obtained from the central composite design were: pH = 5; Fe2+ = 0.1 g/L; H2O2 = 2 g/L; reaction time = 60 min; and electric intensity = 0.2 A. Additionally, optimized experimental conditions were used to study the removal efficiencies of individual 16 PAHs and are also reported. From the close proximity of experimental and predicted results of the software it can be proved that central composite design is efficient enough to be used as a statistical tool in design and analysis for treatment of landfill leachate.

Algae biogas production focusing on operating conditions and conversion mechanisms - A review.

Global warming is the result of traditional fuel use and manufacturing, which release significant volumes of CO2 and other greenhouse gases from factories. Moreover, rising energy consumption, anticipated limitations of fossil fuels in the near future, and increased interest in renewable energies among scientists, currently increase research in biofuels. In contrast to biomass from urban waste materials or the land, algae have the potential to be a commercially successful aquatic energy crop, offering a greater energy potential. Here we discuss the importance of Anaerobic Digestion (AD) for enhanced biogas yield, characterization, and comparisons between algae pretreatment methods namely, mechanical, thermal, microwave irradiation, and enzymatic and catalytic methods. The importance of anaerobic digestion enhances biogas yield, characterization, and comparisons between mechanical, thermal, microwave irradiation, and enzymatic and catalytic treatment. Additionally, operational aspects such as algal species, temperature, C/N ratio, retention period, and particle size impact biofuel yield. The highest algal biogas yield reported was 740 mL/gVS, subtracted from Taihu de-oiled algae applying thermos-chemical pretreatment under conditions of temperature, time, and catalyst concentration of 70 °C, 3 h, and 6%, respectively. Another high yield of algal-based biogas was obtained from Laminaria sp. with mechanical pretreatment under temperature, time, and VS concentration of 38 ± 1 °C, 15 min, and 2.5% respectively, with a maximum yield of 615 ± 7 mL/g VS. Although biofuels derived from algae species are only partially commercialized, the feedstock for biogas might soon be commercially grown. Algae and other plant species that could be cultivated on marginal lands as affordable energy crops with the potential to contribute to the production of biogas are promising and are already being worked on.

Biomass derived green carbon dots for sensing applications of effective detection of metallic contaminants in the environment.

The rapid consumption of metals and unorganized disposal have led to unprecedented increases in heavy metal ion concentrations in the ecosystem, which disrupts environmental homeostasis and results in agricultural biodiversity loss. Mitigation and remediation plans for heavy metal pollution are largely dependent on the discovery of cost-effective, biocompatible, specific, and robust detectors because conventional methods involve sophisticated electronics and sample preparation procedures. Carbon dots (CDs) have gained significant importance in sensing applications related to environmental sustainability. Fluorescence sensor applications have been enhanced by their distinctive spectral properties and the potential for developing efficient photonic devices. With the recent development of biomass-functionalized carbon dots, a wide spectrum of multivalent and bivalent transition metal ions responsible for water quality degradation can be detected with high efficiency and minimal toxicity. This review explores the various methods of manufacturing carbon dots and the biochemical mechanisms involved in metal detection using green carbon dots for sensing applications involving Cu (II), Fe (III), Hg (II), and Cr (VI) ions in aqueous systems. A detailed discussion of practical challenges and future recommendations is presented to identify feasible design routes.

Biotransformation as a tool for remediation of polycyclic aromatic hydrocarbons from polluted environment - review on toxicity and treatment technologies.

Polycyclic aromatic hydrocarbons, a prominent family of persistent organic molecules produced by both anthropogenic and natural processes, are widespread in terrestrial and aquatic environments owing to their hydrophobicity, electrochemical stability and low aqueous solubility. Phenanthrene and naphthalene belong to the group of polycyclic aromatic hydrocarbons whose occurrence are reported to be relatively higher. The bioremediation mode of removing the toxicities of these two compounds has been reported to be promising than other methods. Most of the microbial classes of bacterial, fungal and algal origin are reported to degrade the target pollutants into non-toxic compounds effectively. The review aims to give an overview on toxicological studies, identification and enrichment techniques of phenanthrene and naphthalene degrading microbes and the bioremediation technologies (microbial assisted reactors, microbial fuel cells and microbial assisted constructed wetlands) reported by various researchers. All the three modes of bioremediation techniques were proved to be promising on different perspectives. In the treatment of phenanthrene, a maximum recovery of 96% and 98% was achieved in an aerobic membrane reactor with Bacillus species and single chamber air cathode microbial fuel cell with Acidovorax and Aquamicrobium respectively were reported. With the constructed wetland configuration, 95.5% of removal was attained with manganese oxide based microbial constructed wetland. The maximum degradation efficiency reported for naphthalene are 99% in a reverse membrane bioreactor, 98.5% in a marine sediment microbial fuel cell and 92.8% with a low-cost sandy soil constructed wetland.

Sustainable remediation of toxic congo red dye pollution using bio based carbon nanocomposite: Modelling and performance evaluation.

Remediation of synthetic dyes found in aqueous environment poses a serious challenge for treatment due to their resistance to chemical and biological degradation. This research study investigated the application of Chitosan-ZnO-Seaweed bio nanocomposite in the remediation of congo red. The novel bionanocomposite was characterised by FTIR, SEM, TEM, EDS and XRD studies. The FTIR spectra and SEM images indicated the adsorption of congo red onto the synthesized bionanocomposite. The batch wise experimental studies were done to explore the influence of process variables on removal of congo red from synthetic wastewater and to determine optimized conditions. Under optimized conditions of pH 3, temperature 40 °C, initial congo red concentration 50 mg/L, bionanocomposite quantity 0.03 g/L and interaction period 30 min, the bionanocomposite removed 95.64% of congo red. Thermodynamic studies were carried out and the parameters, ΔH° and ΔS° were found to be 38.386 kJ/mol and 0.1451 kJ/mol. K, respectively. The isotherm and kinetic study showed that monolayer Langmuir model was obeyed (R2 = 0.968) and the experimental value of congo red adsorption correlated well with pseudo second order model (R2 = 0.9938) respectively. The maximum adsorption capacity was found to be 303.03 mg/g. Protonated amino group of chitosan, hydroxyl group of seaweed accounts for congo red adsorption along with zinc oxide.

Adsorptive removal of acid red 18 dye from aqueous solution using hexadecyl-trimethyl ammonium chloride modified nano-pumice.

Discharging untreated dye-containing wastewater gives rise to environmental pollution. The present study investigated the removal efficiency and adsorption mechanism of Acid Red 18 (AR18) utilizing hexadecyl-trimethyl ammonium chloride (HDTMA.Cl) modified Nano-pumice (HMNP), which is a novel adsorbent for AR18 removal. The HDTMA.Cl is characterized by XRD, XRF, FESEM, TEM, BET and FTIR analysis. pH, contact time, initial concentration of dye and adsorbent dose were the four different parameters for investigating their effects on the adsorption process. Response surface methodology-central composite design was used to model and improve the study to reduce expenses and the number of experiments. According to the findings, at the ideal conditions (pH = 4.5, sorbent dosage = 2.375 g/l, AR18 concentration = 25 mg/l, and contact time = 70 min), the maximum removal effectiveness was 99%. The Langmuir (R2 = 0.996) and pseudo-second-order (R2 = 0.999) models were obeyed by the adsorption isotherm and kinetic, respectively. The nature of HMNP was discovered to be spontaneous, and thermodynamic investigations revealed that the AR18 adsorption process is endothermic. By tracking the adsorption capacity of the adsorbent for five cycles under ideal conditions, the reusability of HMNP was examined, which showed a reduction in HMNP's adsorption effectiveness from 99 to 85% after five consecutive recycles.