Tunable third-harmonic generation in a solid-core tellurite glass fiber.

A solid-core tellurite glass fiber with 1.8 dB/m loss at 1.55 µm was made by using the built-in casting preform fabrication method and rod-in-tube fiber drawing technique. Pumping a 10 cm fiber piece with picosecond pulses of 3-5×10(12) W/cm(2), 0.1% of the fundamental power limited by the coherence length of 0.3-5 µm was converted into visible third-harmonic power tunable over a broad near-IR wavelength ranging from 1500 to 1680 nm. Frequency conversion from the mid-IR to near-IR was found to be even more efficient due to the longer coherence lengths of 12-20 µm in the wavelength range of 2200-2500 nm.

Fabrication and characterization of a water-free mid-infrared fluorotellurite glass.

Using a physical and chemical dehydration technique and a high-pressure, ultradry O2 atmosphere in a semiclosed steel-chamber furnace, we fabricated a group of fluorotellurite glasses with a composition of (90-x)TeO2-xZnF2-10Na2O (mol.%, x=0-30). For x=30, no OH absorption was observed in the range of 0.38-6.1 µm. This is the first report of a water-free mid-IR fluorotellurite glass, to our knowledge, offering the common advantages of a robust oxide glass and an IR-transparent fluoride one. Besides optimized linear transmittance and absorption, the nonlinear refractive indices and Raman gain coefficients are reduced. These results are discussed in the context of mid-IR high-power laser generation and transmission.

Second order coherence of broadband down-converted light on ultrashort time scale determined by two photon absorption in semiconductor.

We study the photon correlation properties of broadband parametric down-converted light. The measurement of the photon correlation is carried out thanks to a modified Hanbury Brown-Twiss interferometer based on two photon absorption in GaAs detector. Since this method is not affected by the phase matching conditions of the detecting apparatus (so called "final state post-selection"), the detection bandwidth can be extremely large. This is illustrated by studying, with the same apparatus, the degree of second order coherence of parametric light in both degenerate and non-degenerate cases. We show that our experiment is able to determine the coherent as well as the incoherent contributions to the degree of second order coherence of parametric light with a time resolution in the fs range scale.

Light localization induced enhancement of third order nonlinearities in a GaAs photonic crystal waveguide.

Nonlinear propagation experiments in GaAs photonic crystal waveguides (PCW) were performed, which exhibit a large enhancement of third order nonlinearities, due to light propagation in a slow mode regime, such as two-photon absorption (TPA), optical Kerr effect and refractive index changes due to free-carriers generated by TPA. A theoretical model has been established that shows a very good quantitative agreement with experimental data and demonstrates the important role that the group velocity plays. These observations give a strong insight into the use of PCWs for optical switching devices.

Novel fluorophore based on a multi-substituted olefin skeleton with enhanced three-photon absorption in the femtosecond regime.

A new multipolar fluorophore based on a multi-substituted olefin skeleton that possesses strong three-photon absorption and optical-limiting properties in the femtosecond regime has been designed and synthesized; this archetype suggests a new strategy to further optimize molecular structures toward enhanced nonlinear absorptivities based on known materials.

Multi-photon excitation properties of CdSe quantum dots solutions and optical limiting behavior in infrared range.

Multi-photon absorption and excitation properties of CdSe quantum dots in hexane with different dot-sizes have been investigated. The two- and three-photon absorption (2PA and 3PA) coefficients were measured by using ~160-fs laser pulses at wavelengths of ~775-nm and ~1300-nm, respectively. The dependence of one-, two- and three-photon induced fluorescence spectra as well as their double-exponential decay on the dot-sizes was studied. Based on the fluorescence emission spectra and temporal decay constants for a given sample solution excited by one-, two-and three-photon absorption, it can be concluded that the transition pathways for fluorescence emission and decay under one-, two- and three-photon excitation are nearly identical. The optical power limiting capabilities based on 2PA and 3PA mechanisms are demonstrated separately. In addition, a saturation behavior of 3PA at ~1300 nm was observed.

Significant FRET between SWNT/DNA and rare earth ions: a signature of their spatial correlations.

Significant acceleration of the photoluminescence (PL) decay rate was observed in water solutions of two rare earth ions (REIs), Tb and Eu. We propose that the time-resolved PL spectroscopy data are explained by a fluorescence resonance energy transfer (FRET) between the REIs. FRET was directly confirmed by detecting the induced PL of the energy acceptor, Eu ion, under the PL excitation of the donor ion, Tb, with FRET efficiency reaching 7% in the most saturated solution, where the distance between the unlike REIs is the shortest. Using this as a calibration experiment, a comparable FRET was measured in the mixed solution of REIs with single-wall nanotubes (SWNTs) wrapped with DNA. From the FRET efficiency of 10% and 7% for Tb and Eu, respectively, the characteristic distance between the REI and SWNT/DNA was obtained as 15.9 ± 1.3 Å, suggesting that the complexes are formed because of Coulomb attraction between the REI and the ionized phosphate groups of the DNA.