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1.
Polymers (Basel) ; 14(19)2022 Oct 03.
Artigo em Inglês | MEDLINE | ID: mdl-36236099

RESUMO

Crumb rubber (CR) is one of the materials most widely used in the road infrastructure industry due to its mechanical and environmental benefits as an asphalt binder modifier. Nonetheless, CR decreases the workability of mixes by increasing the viscosity of the binder, leading to an increase in the production temperatures of asphalt mixes. However, warm mix technologies can reduce the temperature demand associated with these processes. The preceding explains the growing interest in producing rubberised asphalt binders incorporating warm mix asphalt (WMA) additives. In this research, the mechanical and rheological properties of a 60/70 penetration grade asphalt binder modified with CR (at a dosage of 15, 18 and 21% by the wet process) and WMA chemical additives (Evotherm M1 and Iterlow T) were investigated. Laboratory tests included penetration, softening point, rotational viscosity, frequency sweep through dynamic shear rheometer (DSR), and multiple stress creep recovery (MSCR) tests. The results indicate that CR increases the stiffness of the asphalt binder, which is reflected in a lower penetration grade and improved softening point. It also improves its rutting resistance but decreases fatigue performance. Furthermore, it has been shown that under the conditions studied, the higher the CR content, the more elevated the degree of stiffness and performance of the asphalt binder. On the other hand, WMA technology decreases asphalt stiffness and performance at high temperatures.

2.
Materials (Basel) ; 13(24)2020 Dec 08.
Artigo em Inglês | MEDLINE | ID: mdl-33302415

RESUMO

The incorporation of a recycled concrete aggregate (RCA) as a replacement of natural aggregates (NA) in road construction has been the subject of recent research. This tendency promotes sustainability, but its use depends mainly on the final product's properties, such as chemical stability. This study evaluates the physical and chemical properties of RCAs from two different sources in comparison with the performance of NA. One RCA was obtained from the demolition of a building (recycled concrete aggregate of a building-RCAB) and another RCA from the rehabilitation of a Portland cement concrete pavement (recycled concrete aggregate from a pavement-RCAP). Characterization techniques such as X-ray fluorescence (XRF), X-ray diffraction (XRD), UV spectroscopy, and atomic absorption spectrometry were used to evaluate the RCAs' coarse fractions for chemical potential effects on asphalt mixtures. NA was replaced with RCA at 15%, 30%, and 45% for each size of the coarse fractions (retained 19.0, 12.5, 9.5, and 4.75 sieves in mm). The mineralogical characterization results indicated the presence of quartz (SiO2) and calcite (CaCO3) as the most significant constituents of the aggregates. XFR showed that RCAs have lower levels of CaO and Al2O3 concerning NA. Potential reactions in asphalt mixtures by nitration, sulfonation, amination of organic compounds, and reactions by alkaline activation in the aggregates were discarded due to the minimum concentration of components such as NO2, (-SO3H), (-SO2Cl), and (Na) in the aggregates. Finally, this research concludes that studied RCAs might be used as replacements of coarse aggregate in asphalt mixtures since chemical properties do not affect the overall chemical stability of the asphalt mixture.

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