Pyrolysis and Gasification of a Real Refuse-Derived Fuel (RDF): The Potential Use of the Products under a Circular Economy Vision.

Refuse-Derived Fuels (RDFs) are segregated forms of wastes obtained by a combined mechanical-biological processing of municipal solid wastes (MSWs). The narrower characteristics, e.g., high calorific value (18-24 MJ/kg), low moisture content (3-6%) and high volatile (77-84%) and carbon (47-56%) contents, make RDFs more suitable than MSWs for thermochemical valorization purposes. As a matter of fact, EU regulations encourage the use of RDF as a source of energy in the frameworks of sustainability and the circular economy. Pyrolysis and gasification are promising thermochemical processes for RDF treatment, since, compared to incineration, they ensure an increase in energy recovery efficiency, a reduction of pollutant emissions and the production of value-added products as chemical platforms or fuels. Despite the growing interest towards RDFs as feedstock, the literature on the thermochemical treatment of RDFs under pyrolysis and gasification conditions still appears to be limited. In this work, results on pyrolysis and gasification tests on a real RDF are reported and coupled with a detailed characterization of the gaseous, condensable and solid products. Pyrolysis tests have been performed in a tubular reactor up to three different final temperatures (550, 650 and 750 °C) while an air gasification test at 850 °C has been performed in a fluidized bed reactor using sand as the bed material. The results of the two thermochemical processes are analyzed in terms of yield, characteristics and quality of the products to highlight how the two thermochemical conversion processes can be used to accomplish waste-to-materials and waste-to-energy targets. The RDF gasification process leads to the production of a syngas with a H2/CO ratio of 0.51 and a tar concentration of 3.15 g/m3.

Environmental and economic impacts of improper materials in the recycling of separated collected food waste through anaerobic digestion and composting.

Separately collected food waste (SC-FW) is effectively recycled through industrial anaerobic digestion (AD) and composting. However, the presence of improper materials in SC-FW not only generates technical problems to AD and composting, but also lowers the quality of the outputs of the processes. As a consequence, improper materials found in SC-FW cause not negligible environmental and economic burdens. In this study, the environmental and economic impacts due to the presence of unsuitable materials in the SC-FW, determined through compositional analysis, were estimated through life cycle assessment and environmental life cycle costing approaches. Three different scenarios were analysed for both AD and composting processes: (i) the current situation (CS); (ii) the improved scenario (AS) with an amount of improper materials in SC-FW reduced to 3 % (w/w); (iii) the ideal scenario (IS) with the total absence of foreign materials. Environmental benefits were determined for the AS and IS scenarios in 17 of the 19 analysed impact categories. Considering the GHG emissions, higher savings were measured for AD in AS and IS scenarios (47 % and 79 %, respectively) than in CS scenario. Similarly, savings of -10.4 kg fossil oil eq/tonSC-FW (AS) and - 17.1 kg fossil oil eq/tonSC-FW (IS) for AD could be obtained with respect to the CS scenario. Greater economic benefits were calculated for AD (-76.4 €/tonSC-FW) and composting (-52.2 €/tonSC-FW) in the IS scenario. Savings up to € 2,249,780 and € 3,888,760 could have been obtained in 2022 by reducing to 3 % (w/w) and eliminating, respectively, the amount of improper materials in the SC-FW. The results of the compositional analyses of SC-FW allowed to identify the incorrect behaviours in FW source-sorting activity and to plan interventions to improve the current FW management system. The quantified environmental and economic benefits could further motivate citizens to correctly differentiate FW.

Environmental sustainability of an integrate anaerobic digestion-composting treatment of food waste: Analysis of an Italian plant in the circular bioeconomy strategy.

In light of the adoption of recent global policies and strategies for a more sustainable food waste management system and a greater control of environmental impacts, this study describes a circular bioeconomy plant model, currently operating in South Italy, for treatment and enhancement of organic fraction of municipal solid waste. The key basis for plant activity is dry anaerobic digestion of separately collected organic fraction of municipal solid waste (SC-OFMSW) followed by digestate composting process. Biomethane for use in the transport sector is obtained by biogas cleaning and upgrading, while high-quality compost for organic farming is produced by digestate composting. Plant activities are completed by the transformation of part of the produced waste into refuse derived fuel (RDF) to be allocated to waste-to-energy plants and the treatment of odour emissions which allows the recovery of ammonium sulphate as a fertilizer. A rooftop photovoltaic system supplies most of electric energy needed by the plant. For plant activities relative to 2020, carbon footprint was equal to -112 kg CO2eq. for Mg of organic waste, while depletion of fossil resources was estimated at -89.6 kg oil eq. Mg-1 of waste. Primary energy demand of food waste treatment system was -2.66 GJ Mg-1 of input waste. Replacement of natural gas with biomethane for transport sector provided the greatest improvement contribution for all the examined categories.

Effects of a temporary increase in OLR and a simultaneous decrease in HRT on dry anaerobic digestion of OFMSW.

The effects of the temporary increase of organic loading rate (OLR) combined with the simultaneous decrease of hydraulic retention time (HRT) on the stability of a pilot scale dry anaerobic digester were investigated. The separately collected organic fraction of municipal solid waste in mesophilic conditions (T = 40°C) was treated. The objective of this study was to verify whether it is possible to feed the digester for short periods, about three consecutive weeks, with higher OLRs and lower HRTs than those considered optimal without generating process failure or long-term instability. Starting from stable operation at a daily OLR of 10.0 kg of total volatile solids (TVS) for digester volume and an HRT of 23 d, the reactor was fed with an OLR of 10.8, 11.7 and 12.5 kg TVS m-3 d-1 corresponding to an HRT of 21, 19 and 18 d, respectively. It was observed that after using an OLR of 10.8 and 11.7 kg TVS m-3 d-1 for 3 weeks with satisfying results, it was possible to restore stable operating conditions at an OLR of 10.0 kg TVS m-3 d-1 in a short time. Otherwise, after using an OLR of 12.5 kg TVS m-3 d-1 the anaerobic digestion was deeply unbalanced and quickly failed. In this latter case, however, it was possible to fully recover and restore the stable conditions of the process within two months.