Photothermal Imaging of Individual Nano-Objects with Large Scattering Cross Sections.

Photothermal (PT) microscopy enables the efficient detection of absorbing nano-objects with high sensitivity and stability. The PT signal in the current PT microscopy usually comes from the interaction of the probe laser beam with the heating laser beam-induced thermal lens, and the contribution of the scattering field from the imaged nano-object is usually not taken into account. Here, in this paper, we systematically studied the influence of the scattering field from the imaged nanoparticles on the obtained PT signal by using Ag nanowires (NWs) on a glass substrate surrounded by glycerol as an example. Under the excitation of a heating laser beam at 532 nm wavelength, the rise of local temperature around the Ag NW results in the intensity variation of the interferometric scattering probe light at 730 nm wavelength which includes the scattering light from the Ag NW and the reflection light from the glass-glycerol interface. We found that the PT signal on the NW are positive and negative for the probe beam polarized parallel and perpendicular to the NW axis, respectively. Numerical simulations confirm that the heat-induced intensity variation of the pure scattering light from the NW and the thermal lens-induced intensity increase of the reflection light both contribute to the obtained PT signal. Our work provides the basic guidance for the analysis of PT signal from nano-objects with large scattering cross sections.

Multiplexed manipulation of orbital angular momentum and wavelength in metasurfaces based on arbitrary complex-amplitude control.

Due to its unbounded and orthogonal modes, the orbital angular momentum (OAM) is regarded as a key optical degree of freedom (DoF) for future information processing with ultra-high capacity and speed. Although the manipulation of OAM based on metasurfaces has brought about great achievements in various fields, such manipulation currently remains at single-DoF level, which means the multiplexed manipulation of OAM with other optical DoFs is still lacking, greatly hampering the application of OAM beams and advancement of metasurfaces. In order to overcome this challenge, we propose the idea of multiplexed coherent pixel (MCP) for metasurfaces. This approach enables the manipulation of arbitrary complex-amplitude under incident lights of both plane and OAM waves, on the basis of which we have realized the multiplexed DoF control of OAM and wavelength. As a result, the MCP method expands the types of incident lights which can be simultaneously responded by metasurfaces, enriches the information processing capability of metasurfaces, and creates applications of information encryption and OAM demultiplexer. Our findings not only provide means for the design of high-security and high-capacity metasurfaces, but also raise the control and application level of OAM, offering great potential for multifunctional nanophotonic devices in the future.

Highly Efficient Ultraviolet Third-Harmonic Generation in an Isolated Thin Si Meta-Structure.

Nonlinear nanophotonic devices have shown great potential for on-chip information processing, quantum source, 3D microfabrication, greatly promoting the developments of integrated optics, quantum science, nanoscience and technologies, etc. To promote the applications of nonlinear nanodevices, improving the nonlinear efficiency, expanding the spectra region of nonlinear response and reducing device thickness are three key issues. Herein, this study focuses on the nonlinear effect of third-harmonic generation (THG), and present a thin Si meta-sructure to improve the THG efficiency in the ultraviolet (UV) region. The measured THG efficiency is up to 10-5 at an emission wavelength of 309 nm. Also, the THG nanosystem is only 100 nm in thickness, which is two-five times thinner than previous all-dielectric nanosystems applied in THG studies. These findings not only present a powerful thin meta-structure with highly efficient THG emission in UV region, but also provide a constructive avenue for further understanding the light-matter interactions at subwavelength scales, guiding the design and fabricating of advanced photonic devices in future.

Au@Ag Nanorods-PDMS Wearable Mouthguard as a Visualized Detection Platform for Screening Dental Caries and Periodontal Diseases.

The development of easy-to-use, low-cost, and visualized detection platforms for screening human dental caries and periodontal diseases is in urgent demand. In this work, a Au@Ag nanorods-poly(dimethylsiloxane) (Au@Ag NRs-PDMS) wearable mouthguard, which can visualize the tooth lesion sites through the color change of it at the corresponding locations, is presented. The Au@Ag NRs-PDMS composite exhibits a distinct color response to hydrogen sulfide (H2 S) gas generated by bacterial decay at the lesion sites. Moreover, the Au@Ag NRs-PDMS mouthguard is demonstrated to own desired mechanical properties, excellent chemical stability, as well as good biocompatibility, and can accurately locate the lesion sites in human oral cavity. These findings suggest that the mouthguard has the potential to be utilized on a large scale to help people self-monitor their oral health in daily life, and treat oral diseases locally.

Resonant scattering-enhanced photothermal microscopy.

Photothermal (PT) microscopy is currently the most efficient approach for the detection and spectroscopy of individual non-fluorescent nano-objects based solely on their absorption. The nano-objects in current PT microscopy are usually non-resonant with the probe laser light, and the PT signal is mainly generated from the interactions of the incident probe light and the heating light-induced thermal lens around the imaged object. Inspired by the high sensitivity of the scattering field from the nano-objects near optical resonance to the variation in the local refractive index, we developed a novel strategy of resonant scattering-enhanced PT microscopy where the imaged nano-objects are near-resonant with the probe laser light. We have demonstrated this by using gold nanorods (NRs) with tunable longitudinal surface plasmon resonances. The PT signal of gold NR near-resonant with the probe light showed dramatic variation in the narrow resonance wavelength range, as small as 15 nm, and the maximal amplitude of the PT signal in this range can be enhanced up to 43 times as compared with the weak PT signal of gold NR non-resonant with the probe light. Theoretical analysis indicates that the obtained strong PT signal is mainly caused by the heat-induced variation in the polarizability of gold NR. Our novel work demonstrates the first resonant scattering-enhanced PT imaging of plasmonic nanoparticles, paving the way for the development of PT microscopy with ultra-high sensitivity toward the sensing, imaging, and spectroscopy of nanoscopic objects in complex environments.

Resonant scattering enhanced interferometric scattering microscopy.

Interferometric scattering (iSCAT) microscopy is a powerful tool for high-sensitive label-free imaging and sensing of nano-objects with high spatial-temporal resolution. The nano-objects imaged with the current iSCAT microscopy are usually non-resonant under laser light illumination and the iSCAT signal contrast is simply proportional to the volume and weight of the objects of interest. Here in this paper, we developed a novel strategy of resonant scattering enhanced iSCAT microscopy where the imaged nanoparticles are near resonant under laser light illumination, and we demonstrated it by using gold nanorods (NRs) with tunable longitudinal surface plasmon resonances. The obtained iSCAT signal contrast shows a dramatic variation in the narrow resonance wavelength range as small as 20 nm, and this is attributed to the strong wavelength dependence of the polarizability of gold NRs under optical resonance conditions. Different factors that have contributed to the iSCAT signal are theoretically analyzed and numerically simulated, providing the basic understanding about the effect of optical resonance on the iSCAT signal of nanoparticles. Our novel work provides a promising approach toward resonant sensing, imaging, and spectroscopy of nanoscopic objects.