How does exotic Spartina alterniflora affect the contribution of iron-bound organic carbon to soil organic carbon in salt marshes?

Iron-bound organic carbon (OC-FeR) is important for the stability of soil organic carbon (SOC) in salt marshes, and the Spartina alterniflora invasion reshaped local salt marshes and changed the SOC pool. To evaluate the effects of S. alterniflora invasion on the contribution of OC-FeR to SOC, we determined the OC-FeR content and soil characteristics in the 0-50 cm soil profile along the vegetation sequence, including mudflats (MF), S. alterniflora marshes established in 2003 (SA03) and 1989 (SA89), the ecotone of S. alterniflora and Phragmites australis (SE), S. salsa marsh (SS), and P. australis marsh (PA). The SOC content was 6.55-17.5 mg g-1 in the S. alterniflora marshes. Reactive iron oxides (Fed, Feo, Fep) accumulated significantly in the S. alterniflora and P. australis salt marshes. PA and S. alterniflora marshes had higher DOC contents of 0.28-0.77 mg g-1. The OC-FeR content in the 0-50 cm soil profile in these ecosystems ranged from 0.3 to 3.29 mg g-1, with a contribution to the SOC content (fOC-FeR) of approximately 11 %, which was highest in SA03 (16.3 % ~ 18.8 %), followed by SA89, SE, and PA. In addition, the molar ratios of OC-FeR to Fed were <1, indicating that the iron oxides were associated with SOC through sorption more than coprecipitation. According to the structural equation model, SOC, DOC and iron oxides were the direct driving factors of OC-FeR formation, while the vegetation zone indirectly functioned by regulating organic C inputs, iron oxide formation, and pH. This study suggested that S. alterniflora invasion promotes iron-bound organic carbon accumulation by increasing organic C inputs and regulating iron oxide formation in salt marshes, but such promotion will degenerate with development duration.

Extraction and Reconstruction of Arbitrary 3D Frequency Features from the Potassium Dihydrogen Phosphate Surfaces Machined by Different Cutting Parameters.

To comprehensively analyze the effect of cutting parameters on the 3D surface topography of machined potassium dihydrogen phosphate crystals, 2D power spectrum density and continuous wavelet transform are used to extract and reconstruct the arbitrary actual 3D frequency features of machined potassium dihydrogen phosphate crystal surfaces. The 2D power spectrum density method is used to quantitatively describe the 3D surface topography of machined potassium dihydrogen phosphate crystals. The continuous wavelet transform method is applied to extract and reconstruct 3D topographies of arbitrary actual spatial frequency features in machined surfaces. The main spatial frequency features fx of the machined surfaces are 0.0056 µm-1, 0.0112 µm-1, and 0.0277 µm-1 with the cutting depth from 3 µm to 9 µm. With the feed rate changing from 8µm/r to 18 µm/r, the main spatial frequency features fx are 0.0056 µm-1-0.0277 µm-1. With the spindle speed from 1300 r/min to 1500 r/min, the main spatial frequency features fx are same as the main spatial frequency features of the cutting depths. The results indicate that the variation of cutting parameters affects the main spatial frequency features on the 3D surface topography. The amplitudes of the spatial middle-frequency features are increased with the increasing of cutting depth and spindle speed. The spatial low-frequency features are mainly affected via the feed rate. The spatial high-frequency features are related to the measurement noise and material properties of potassium dihydrogen phosphate. The distributional directions of the frequency features in the reconstructed 3D surface topography are consistent with the distribution directions of actual frequency features in the original surface topography. The reconstructed topographies of the spatial frequency features with maximum power spectrum density are the most similar to the original 3D surfaces. In this machining, the best 3D surface topography of the machined KDP crystals is obtained with a cutting depth ap = 3 µm, feed rate f = 8 µm/r and a spindle speed n = 1400 r/min.