Quantum cascade laser.

A semiconductor injection laser that differs in a fundamental way from diode lasers has been demonstrated. It is built out of quantum semiconductor structures that were grown by molecular beam epitaxy and designed by band structure engineering. Electrons streaming down a potential staircase sequentially emit photons at the steps. The steps consist of coupled quantum wells in which population inversion between discrete conduction band excited states is achieved by control of tunneling. A strong narrowing of the emission spectrum, above threshold, provides direct evidence of laser action at a wavelength of 4.2 micrometers with peak powers in excess of 8 milliwatts in pulsed operation. In quantum cascade lasers, the wavelength, entirely determined by quantum confinement, can be tailored from the mid-infrared to the submillimeter wave region in the same heterostructure material.

Highly efficient light-emitting diodes with microcavities.

One-dimensional microcavities are optical resonators with coplanar reflectors separated by a distance on the order of the optical wavelength. Such structures quantize the energy of photons propagating along the optical axis of the cavity and thereby strongly modify the spontaneous emission properties of a photon-emitting medium inside a microcavity. This report concerns semiconductor light-emitting diodes with the photon-emitting active region of the light-emitting diodes placed inside a microcavity. These devices are shown to have strongly modified emission properties including experimental emission efficiencies that are higher by more than a factor of 5 and theoretical emission efficiencies that are higher by more than a factor of 10 than the emission efficiencies in conventional light-emitting diodes.

Self-mode-locking of quantum cascade lasers with giant ultrafast optical nonlinearities.

We report on the generation of picosecond self-mode-locked pulses from midinfrared quantum cascade lasers, at wavelengths within the important molecular fingerprint region. These devices are based on intersubband electron transitions in semiconductor nanostructures, which are characterized by some of the largest optical nonlinearities observed in nature and by picosecond relaxation lifetimes. Our results are interpreted with a model in which one of these nonlinearities, the intensity-dependent refractive index of the lasing transition, creates a nonlinear waveguide where the optical losses decrease with increasing intensity. This favors the generation of ultrashort pulses, because of their larger instantaneous intensity relative to continuous-wave emission.

Detection of biogenic CO production above vascular cell cultures using a near-room-temperature QC-DFB laser.

We report the first application of pulsed, near-room-temperature quantum cascade laser technology to the continuous detection of biogenic CO production rates above viable cultures of vascular smooth muscle cells. A computer-controlled sequence of measurements over a 9-h period was obtained, resulting in a minimum detectable CO production of 20 ppb in a 1-m optical path above a standard cell-culture flask. Data-processing procedures for real-time monitoring of both biogenic and ambient atmospheric CO concentrations are described.

Spectroscopic detection of biological NO with a quantum cascade laser.

Two configurations of a continuous wave quantum cascade distributed feedback laser-based gas sensor for the detection of NO at a parts per billion (ppb) concentration level, typical of biomedical applications, have been investigated. The laser was operated at liquid nitrogen temperature near lambda = 5.2 microns. In the first configuration, a 100 m optical path length multi-pass cell was employed to enhance the NO absorption. In the second configuration, a technique based on cavity-enhanced spectroscopy (CES) was utilized, with an effective path length of 670 m. Both sensors enabled simultaneous analysis of NO and CO2 concentrations in exhaled air. The minimum detectable NO concentration was found to be 3 ppb with a multi-pass cell and 16 ppb when using CES. The two techniques are compared, and potential future developments are discussed.

Absorption spectroscopy with quantum cascade lasers.

Novel pulsed and cw quantum cascade distributed feedback (QC-DFB) lasers operating near lambda=8 micrometers were used for detection and quantification of trace gases in ambient air by means of sensitive absorption spectroscopy. N2O, 12CH4, 13CH4, and different isotopic species of H2O were detected. Also, a highly selective detection of ethanol vapor in air with a sensitivity of 125 parts per billion by volume (ppb) was demonstrated.

Coupled-cavity resonant passive mode-locked Nd:yttrium lithium fluoride laser.

We report coupled-cavity resonant passive mode locking of a Nd:YLF laser. This technique has produced 4-ps pulses at a wavelength of 1.047 microm with 390-mW average power at a 250-MHz repetition rate, corresponding to a 1.6-nJ pulse energy. The Nd:YLF rod was pumped with 1.5 W of power at 798 nm from a Ti:sapphire laser. The nonlinear reflector used in the coupled cavity was an InGaAs/GaAs strained layer multiple-quantum-well sample.

Near-perfect correlation of the resistance components of mesoscopic samples at the quantum Hall regime.

We study the four-terminal resistance fluctuations of mesoscopic samples near the transition between the nu=2 and the nu=1 quantum Hall states. We observe near-perfect correlations between the fluctuations of the longitudinal and Hall components of the resistance. These correlated fluctuations appear in a magnetic-field range for which the two-terminal resistance of the samples is quantized. We discuss these findings in light of edge-state transport models of the quantum Hall effect. We also show that our results lead to an ambiguity in the determination of the width of quantum Hall transitions.

Observation of a quantized hall resistivity in the presence of mesoscopic fluctuations.

We present an experimental study of mesoscopic, two-dimensional electronic systems at high magnetic fields. Our samples, prepared from a low-mobility InGaAs/InAlAs wafer, exhibit reproducible, sample specific, resistance fluctuations. Focusing on the lowest Landau level, we find that, while the diagonal resistivity displays strong fluctuations, the Hall resistivity is free of fluctuations and remains quantized at its nu=1 value, h/e(2). This is true also in the insulating phase that terminates the quantum Hall series. These results extend the validity of the semicircle law of conductivity in the quantum Hall effect to the mesoscopic regime.

Dual-wavelength emission from optically cascaded intersubband transitions.

Dual-wavelength intersubband emission at 8 and 10 microm is reported in a three-level quantum-well system in which one electronic state is at the same time the lower level of the first optical transition and the upper level of the second. Results are presented for two different AlInAs/GaInAs quantum cascade structures featuring single-well active regions with two vertical transitions or double-well active regions with one diagonal and one vertical transition. Laser action has been achieved between the excited states of the single-well device and on the diagonal transition of the double-well structure. In the latter case the wavelength can be electric-field tuned by means of the Stark effect also above threshold.

Long-wavelength (lambda approximately 8-11.5 microm) semiconductor lasers with waveguides based on surface plasmons.

Laser waveguides based on surface plasmons at a metal-semiconductor interface have been demonstrated by use of quantum cascade (QC) lasers emitting in the 8-11.5-microm wavelength range. The guided modes are transverse magnetic polarized surface waves that propagate at the metal (Pd or Ti-Au)-semiconductor interface between the laser top contact and the active region without the necessity for waveguide cladding layers. The resultant structure has the advantages of a strong decrease in the total layer thickness and a higher confinement factor of the laser-active region compared with those of a conventional layered semiconductor waveguide, and strong coupling to the active material, which could be used in devices such as distributed-feedback lasers. These advantages have to be traded against the disadvantage of increased absorption losses. A peak output power exceeding 25 mW at 90 K and a maximum operating temperature of 150 K were measured for a QC laser with an emission wavelength lambda approximately 8 microm . At lambda approximately 11.5 microm the peak power levels are several milliwatts and the maximum operating temperature is 110 K.

High-power, continuous-wave, current-tunable, single-mode quantum-cascade distributed-feedback lasers at lambda - 5.2 and lambda - 7.95 mum.

Quantum-cascade distributed-feedback lasers with high-power, continuous-wave (cw), tunable, single-mode emission are reported. The emission wavelengths are near 5.2 and 7.95 mum. The lasers are operated at liquid-nitrogen temperature and above. A maximum output power of >100 mW is obtained per facet at 80 K for both wavelengths, which is the result of careful positioning of the peak gain with respect to the Bragg wavelength. Continuous tuning with either heat-sink temperature or cw current is demonstrated. The tuning coefficients are 0.35 nm/K (5.2 mum) and 0.51 nm/K(7.95 mum) for thermal tuning and vary from 20 to 40 nm/A for tuning with current. The lasers are being used in high-resolution and high-sensitivity gas-sensing applications.

Methane concentration and isotopic composition measurements with a mid-infrared quantum-cascade laser.

A quantum-cascade laser operating at a wavelength of 8.1 micrometers was used for high-sensitivity absorption spectroscopy of methane (CH4). The laser frequency was continuously scanned with current over more than 3 cm-1, and absorption spectra of the CH4 nu 4 P branch were recorded. The measured laser linewidth was 50 MHz. A CH4 concentration of 15.6 parts in 10(6) ( ppm) in 50 Torr of air was measured in a 43-cm path length with +/- 0.5-ppm accuracy when the signal was averaged over 400 scans. The minimum detectable absorption in such direct absorption measurements is estimated to be 1.1 x 10(-4). The content of 13CH4 and CH3D species in a CH4 sample was determined.

Free-running frequency stability of mid-infrared quantum cascade lasers.

The intrinsic frequency fluctuations of two single-mode quantum cascade (QC) distributed-feedback lasers operating continuously at a wavelength of 8.5 mum are reported. A Doppler-limited rovibrational resonance of nitrous oxide is used to transform the frequency noise into measurable intensity fluctuations. The QC lasers, along with recently improved current controllers, exhibit a free-running frequency stability of 150 kHz over a 15-ms time interval.

Sensitive absorption spectroscopy with a room-temperature distributed-feedback quantum-cascade laser.

We report what we believe are the first spectroscopic measurements to be made with a room-temperature quantum-cascade distributed-feedback laser. Using wavelength modulation spectroscopy, we detected N(2)O and CH(4) in the chemical fingerprint wavelength range near 8microm . The noise equivalent absorbance for our measurement was 5 parts in 10(5), limited by excess amplitude modulation on the laser output, which corresponds to a 1-Hz bandwidth detection limit of 250 parts N(2)O in 10(9) parts N(2) in a 1-m path length.

High-resolution (Doppler-limited) spectroscopy using quantum-cascade distributed-feedback lasers.

Lasing characteristics were evaluated for distributed-feedback quantum-cascade (QC) lasers operating in a continuous mode at cryogenic temperatures. These tests were performed to determine the QC lasers' suitability for use in high-resolution spectroscopic applications, including Doppler-limited molecular absorption and pressure-limited lidar applications. By use of a rapid-scan technique, direct absorbance measurements of nitric oxide (NO) and ammonia (NH>(3)) were performed with several QC lasers, operating at either 5.2 or 8.5 microm. Results include time-averaged linewidths of better than 40 MHz and long-term laser frequency reproducibility, even after numerous temperature cycles, of 80 MHz or better. Tuning rates of 2.5 cm(-1) in 0.6 ms can be easily achieved. Noise-equivalent absorbance of 3 x 10(-6) was also obtained without optimizing the optical arrangement.

Application of Balanced Detection to Absorption Measurements of Trace Gases with Room-Temperature, Quasi-cw Quantum-Cascade Lasers.

Distributed-feedback quantum-cascade (QC) lasers are expected to form the heart of the next-generation mid-IR laser absorption spectrometers, especially as they are applied to measurements of trace gases in a variety of environments. The incorporation of room-temperature-operable, single-mode QC lasers should result in highly compact and rugged sensors for real-world applications. We report preliminary results on the performance of a laser absorption spectrometer that uses a QC laser operating at room temperature in a quasi-cw mode in conjunction with balanced ratiometric detection. We have demonstrated sensitivities for N(2)O [10 parts in 10(6) volume-mixing ratio for a 1-m path (ppmv-m)] and NO [520 parts in 10(9) volume-mixing ratio for a 1-m path (ppbv-m)] at 5.4 mum. System improvements are described that are expected to result in a 2 orders of magnitude increase in sensitivity.

Cavity ringdown spectroscopic detection of nitric oxide with a continuous-wave quantum-cascade laser.

A spectroscopic gas sensor for nitric oxide (NO) detection based on a cavity ringdown technique was designed and evaluated. A cw quantum-cascade distributed-feedback laser operating at 5.2 mum was used as a tunable single-frequency light source. Both laser-frequency tuning and abrupt interruptions of the laser radiation were performed through manipulation of the laser current. A single ringdown event sensitivity to absorption of 2.2 x 10(-8) cm(-1) was achieved. Measurements of parts per billion (ppb) NO concentrations in N(2) with a 0.7-ppb standard error for a data collection time of 8 s have been performed. Future improvements are discussed that would allow quantification of NO in human breath.

Quantitative gas sensing by backscatter-absorption measurements of a pseudorandom code modulated lambda ~ 8-microm quantum cascade laser.

We have demonstrated quantitative chemical vapor detection with a multimode quantum cascade (QC) laser. Experiments incorporated pseudorandom code (PRC) modulation of the laser intensity to permit sensitive absorption measurements of isopropanol vapor at 8.0micro . The demonstration shows the practicality of one technical approach for implementing low-peak-power QC lasers in the transmitter portion of a differential absorption lidar (DIAL) system. With a 31-chip, 300-ns/chip PRC sequence, the measured isopropanol detection limit was 12 parts in 10(6) by volume times meters (~3x10(-3) absorption) for a simple backscatter-absorption measurement configuration.

Trace-gas detection in ambient air with a thermoelectrically cooled, pulsed quantum-cascade distributed feedback laser.

A pulsed quantum-cascade distributed feedback laser operating at near room temperature was used for sensitive high-resolution IR absorption spectroscopy of ambient air at a wavelength of approximately 8 microm. Near-transform-limited laser pulses were obtained owing to short (approximately 5-ns) current pulse excitation and optimized electrical coupling. Fast and slow computer-controlled frequency scanning techniques were implemented and characterized. Fast computer-controlled laser wavelength switching was used to acquire second-derivative absorption spectra. The minimum detectable absorption was found to be 3 x 10(-4) with 10(5) laser pulses (20-kHz repetition rate), and 1.7 x 10(-4) for 5 x 10(5) pulses, based on the standard deviation of the linear regression analysis.