Alkylphenol ethoxylate metabolites in coastal sediments off southwestern Taiwan: Spatiotemporal variations, possible sources, and ecological risk.

Alkylphenol ethoxylates (APEOs) are one of the most widely used classes of surfactants, but they are also ubiquitous environmental pollutants and known endocrin-disrupting chemicals. This study is the first to investigate the spatiotemporal variations and possible sources of APEOs and their metabolites, including nonylphenol ethoxylates (NPEOs) and octylphenol ethoxylates (OPEOs), in coastal sediments off southwestern Taiwan. The highest APEO concentration in the dry season was observed for the Kaohsiung coastal area, whereas the highest alkylphenol (AP) concentration in the wet season was found offshore at the Tainan Canal exit. No continuous accumulation of alkylphenol metabolites was evident in the area. One possible reason is that seasonal current and wind waves disperse the coastal pollutants. Application of multivariate statistical tools (hierarchical cluster analysis and principal component analysis) confirmed the role of rivers and the Tainan Canal in transporting contaminants to coastal environments, suggesting influences of industrial and human activities on APEO distribution. A further comparison with the predicted no-effect concentrations (PNECs) proposed by the European Union indicates that nonylphenol (NP) and octylphenol (OP) might pose potential ecological risks to the aquatic environment in the studied area. These findings provide useful information for environmental policy implementation and ecological assessments of different types of endocrine-disrupting chemicals and raise warnings about surfactant applications.

Textural, surface and chemical properties of polyvinyl chloride particles degraded in a simulated environment.

Virgin polyvinyl chloride (PVC) particles were exposed to heat, ultraviolet B (UVB) and solar radiation either in artificial seawater or in air for different periods of time. The surface and chemical properties of fresh and degraded particle surfaces were determined via image analysis using scanning electron micrographs, a Brunauer-Emmett-Teller (BET) specific surface area analyzer and infrared spectroscopy. Thermal and UVB degradation resulted in unique PVC morphologies. In addition, the increased presences of functional groups were evident as dehydrochlorination and oxidation during the degradation process, which altered the chemical properties of PVC. In contrast, under solar exposure with or without seawater, unevenness to the surface was noted that seems to originate from degradation of the PVC surface; in addition, no new functional groups were found. This suggests that the chemical properties of PVC are stable over extended periods in the marine environment.