Effect of sodium oxide content on the formation of nanogratings in germanate glass by a femtosecond laser.

We report on the formation and structural evolution of embedded self-organized, polarization-dependent nanogratings in sodium germanate glasses induced by an 800 nm, 1 kHz femtosecond laser. Optical birefringence dependent on the femtosecond laser polarization as well as the sodium oxide content is observed when the sample surface is perpendicular to the laser propagation direction. Scanning electron microscopy images of the written lines reveal the formation of periodic platelet or nanovoid arrays, which are aligned perpendicularly to the laser polarization direction after mechanical polishing. The influences of sodium oxide content on the morphology and period of the nanogratings are discussed.

Enhanced broadband excited upconversion luminescence in Ho-doped glasses by codoping with bismuth.

We report enhanced green and red upconversion (UC) luminescence in Ho3+-doped oxyfluoride germanate glass by introducing bismuth near-infrared active centers as sensitizers. The UC excitation bands at 750 and 970 nm show a full width at half-maximum of 20 and 45 nm, respectively. Energy transfer from sensitizers, the excited-state absorption, and phonon-coupled absorption of Ho3+ jointly contribute to the enhanced UC luminescence. Our approach provides an efficient methodology to broaden the excitation bandwidth of UC luminescent materials, which may have the potential for promising application in solar cells.

Regulation of structure rigidity for improvement of the thermal stability of near-infrared luminescence in Bi-doped borate glasses.

The effect of heat-treatment on the near-infrared (NIR) luminescence properties was studied in Bi-doped borate glasses. The luminescence intensity generally decreases with the increase of temperature, and the thermal stability can be improved by nearly 4.5 times with addition of 5 mol% La2O3. Collaborative studies by using steady photoluminescence (PL) and photoluminescence excitation (PLE) spectra, luminescence decay curve, differential thermal analysis (DTA), Raman spectra and X-ray diffraction (XRD) indicate that the luminescence decrement is associated with the agglomeration of Bi active centers during heat-treatment. The improvement of the thermal stability of NIR luminescence with the addition of La2O3 is benefited from the enhancement of structure rigidity due to the strong cationic field strength of La3+. The results not only provide valuable guidance for suppressing performance degradation of Bi-doped glass during fiber drawing process, but also present an effective way to control the luminescence properties of main group elements in glasses from the perspective of glass structure.