Equivalence of the Wei potential model and Tietz potential model for diatomic molecules.

By employing the dissociation energy and the equilibrium bond length for a diatomic molecule as explicit parameters, we generate improved expressions for the well-known Rosen-Morse, Manning-Rosen, Tietz, and Frost-Musulin potential energy functions. It is found that the well-known Tietz potential function that is conventionally defined in terms of five parameters [T. Tietz, J. Chem. Phys. 38, 3036 (1963)] actually only has four independent parameters. It is shown exactly that the Wei [Phys. Rev. A 42, 2524 (1990)] and the well-known Tietz potential functions are the same solvable empirical function. When the parameter h in the Tietz potential function has the values 0, +1, and -1, the Tietz potential becomes the standard Morse, Rosen-Morse, and Manning-Rosen potentials, respectively.

Photocatalytic Mechanism Regulation of Bismuth Oxyhalogen via Changing Atomic Assembly Method.

Exciton and carrier photocatalytic processes have been proved in bismuth oxyhalogen photocatalysts. But, there are no reports about how to regulate the different mechanisms to improve photocatalytic activity for different reaction. Here, we found that the photocatalytic mechanisms could be regulated by changing the assembly method of bismuth, oxygen, and halogen atoms. Reactive oxygen species (ROS) experimentals results concluded that solid solution BiOBr0.5I0.5 showed enhanced exciton photocatalytic process, and coupling 0.5BiOBr/0.5BiOI displayed improved carrier photocatalytic proces. This work promoted the understanding about solid solution and coupling for bismuth oxyhalogen.