1.
Org Biomol Chem
; 21(1): 75-79, 2022 12 21.
Artigo
em Inglês
| MEDLINE
| ID: mdl-36448655
RESUMO
A palladium-catalyzed ß-C(sp3)-H nitrooxylation of aliphatic alcohols with AgNO2 is reported. An 8-formylquinoline-derived oxime is installed as an exo-type directing group for sp3 C-H activation and selectfluor acts as the oxidant. The reaction tolerates a variety of functional groups and shows good selectivity for ß-C-H nitrooxylation of alcohols.