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Stretchable strain sensors play a crucial role in intelligent wearable systems, serving as the interface between humans and environment by translating mechanical strains into electrical signals. Traditional fiber strain sensors with intrinsic uniform axial strain distribution face challenges in achieving high sensitivity and anisotropy. Moreover, existing micro/nano-structure designs often compromise stretchability and durability. To address these challenges, a novel approach of using 3D printing to fabricate MXene-based flexible sensors with tunable micro and macrostructures. Poly(tetrafluoroethylene) (PTFE) as a pore-inducing agent is added into 3D printable inks to achieve controllable microstructural modifications. In addition to microstructure tuning, 3D printing is employed for macrostructural design modifications, guided by finite element modeling (FEM) simulations. As a result, the 3D printed sensors exhibit heightened sensitivity and anisotropy, making them suitable for tracking static and dynamic displacement changes. The proposed approach presents an efficient and economically viable solution for standardized large-scale production of advanced wire strain sensors.
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Zinc-iodine (Zn-I2) batteries have garnered significant attention for their high energy density, low cost, and inherent safety. However, several challenges, including polyiodide dissolution and shuttling, sluggish iodine redox kinetics, and low electrical conductivity, limit their practical applications. Herein, we designed a highly efficient electrocatalyst for Zn-I2 batteries by uniformly dispersing Ni single atoms (NiSAs) on hierarchical porous carbon skeletons (NiSAs-HPC). In situ Raman analysis revealed that the conversion of soluble polyiodides (I3- and I5-) was significantly accelerated using NiSAs-HPC because of the remarkable electrocatalytic activity of NiSAs. The resulting Zn-I2 batteries with NiSAs-HPC/I2 cathodes delivered exceptional rate capability (121 mAh g-1 at 50 C), and ultralong cyclic stability (over 40â¯000 cycles at 50 C). Even under 11.6 mg cm-2 iodine, Zn-I2 batteries still exhibited an impressive cyclic stability with a capacity retention of 93.4% and 141 mAh g-1 after 10â¯000 cycles at 10 C.
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In this study, we introduce a novel approach for synthesizing two-dimensional (2D) MXene heterostructures featuring a sandwiched and cross-linked network structure. This method addresses the common issue of activity degradation in 2D nanomaterials caused by inevitable aggregation. By utilizing the distinct surface characteristics of MXene, we successfully induced the growth of various 2D nanomaterials on MXene substrates. This strategy effectively mitigates self-stacking defects and augments the exposure of surface areas. In particular, the obtained 2D-2D MXene@NiCo-layered double hydroxide (MH-NiCo) heterostructures exhibit enhanced structural stability, improved chemical reversibility, and heightened charge transfer efficiency, outperforming pure NiCo LDH. The aqueous MH-Ni4Co1//Zn@carbon cloth (MH-Ni4Co1//Zn@CC) battery demonstrates exceptional performance with a remarkable specific capacity of 0.61â mAh cm-2, maintaining 96.6 % capacitance after 2300â cycles. Additionally, it achieves an energy density of 1.047â mWh cm-2 and a power density of 32.899â mW cm-2. This research not only paves the way for new design paradigms in energy-related nanomaterials but also offers invaluable insights for the application and optimization of 2D-2D heterostructures in advanced electrochemical devices.
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Vanadium-based oxides with high theoretical specific capacities and open crystal structures are promising cathodes for aqueous zinc-ion batteries (AZIBs). In this work, the confined synthesis can insert metal ions into the interlayer spacing of layered vanadium oxide nanobelts without changing the original morphology. Furthermore, we obtain a series of nanomaterials based on metal-confined nanobelts, and describe the effect of interlayer spacing on the electrochemical performance. The electrochemical properties of the obtained Al2.65 V6 O13 â 2.07H2 O as cathodes for AZIBs are remarkably improved with a high initial capacity of 571.7â mAh â g-1 at 1.0â A g-1 . Even at a high current density of 5.0â A g-1 , the initial capacity can still reach 205.7â mAh g-1 , with a high capacity retention of 89.2 % after 2000â cycles. This study demonstrates that nanobelts confined with metal ions can significantly improve energy storage applications, revealing new avenues for enhancing the electrochemical performance of AZIBs.
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Aqueous ammonium-ion storage has been considered a promising energy storage competitor to meet the requirements of safety, affordability, and sustainability. However, ammonium-ion storage is still in its infancy in the absence of reliable electrode materials. Here, defective VO2 (d-VO) is employed as an anode material for ammonium-ion batteries with a moderate transport pathway and high reversible capacity of ≈200 mAh g-1 . Notably, an anisotropic or anisotropic behavior of structural change of d-VO between c-axis and ab planes depends on the state of charge (SOC). Compared with potassium-ion storage, ammonium-ion storage delivers a higher diffusion coefficient and better electrochemical performance. A full cell is further fabricated by d-VO anode and MnO2 cathode, which delivers a high energy density of 96 Wh kg-1 (based on the mass of VO2 ), and a peak energy density of 3254 W kg-1 . In addition, capacity retention of 70% can be obtained after 10 000 cycles at a current density of 1 A g-1 . What's more, the resultant quasi-solid-state MnO2 //d-VO full cell based on hydrogel electrolyte also delivers high safety and decent electrochemical performance. This work will broaden the potential applications of the ammonium-ion battery for sustainable energy storage.
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Lithium-sulfur (Li-S) batteries with high theoretical energy density have caught enormous attention for electrochemical power source applications. However, the development of Li-S batteries is hindered by the electrochemical performance decay that resulted from low electrical conductivity of sulfur and serious shuttling effect of intermediate polysulfides. Moreover, the areal capacity is usually restricted by the low areal sulfur loadings (1.0-3.0 mg cm-2). When the areal sulfur loading increases to a practically accepted level above 3.0-5.0 mg cm-2, the areal capacity and cycling life tend to become inferior. Herein, we report an effective polysulfide mediator composed of nitrogen-doped carbon nanotube (N-CNT) forest planted on cobalt nanoflowers (N-CNTs/Co-NFs). The abundant pores in N-CNTs/Co-NFs can allow a high sulfur content (78 wt %) and block the dissolution/diffusion of polysulfides via physical confinement, and the Co nanoparticles and nitrogen heteroatoms (4.3 at. %) can enhance the polysulfide retention via strong chemisorption capability. Moreover, the planted N-CNT forest on N-CNTs/Co-NFs can enable fast electron transfer and electrolyte penetration. Benefiting from the above merits, the sulfur-filled N-CNTs/Co-NFs (S/N-CNTs/Co-NFs) cathodes with high areal sulfur loadings exhibit low self-discharge rate, high areal capacity, and stable cycling performance.
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The catalytic conversion of nitrogen to ammonia is one of the most important processes in nature and chemical industry. However, the traditional Haber-Bosch process of ammonia synthesis consumes substantial energy and emits a large amount of carbon dioxide. Solar-driven nitrogen fixation holds great promise for the reduction of energy consumption and environmental pollution. On the basis of both experimental results and density functional theory calculations, here we report that the oxygen vacancy engineering on ultrathin BiOBr nanosheets can greatly enhance the performance for photocatalytic nitrogen fixation. Through the addition of polymetric surfactant (polyvinylpyrrolidone, PVP) in the synthesis process, VO-BiOBr nanosheets with desirable oxygen vacancies and dominant exposed {001} facets were successfully prepared, which effectively promote the adsorption of inert nitrogen molecules at ambient condition and facilitate the separation of photoexcited electrons and holes. The oxygen defects narrow the bandgap of VO-BiOBr photocatalyst and lower the energy requirement of exciton generation. In the case of the specific surface areas are almost equal, the VO-BiOBr nanosheets display a highly improved photocatalytic ammonia production rate (54.70 µmol·g-1·h-1), which is nearly 10 times higher than that of the BiOBr nanoplates without oxygen vacancies (5.75 µmol·g-1·h-1). The oxygen vacancy engineering on semiconductive nanomaterials provides a promising way for rational design of catalysts to boost the rate of ammonia synthesis under mild conditions.
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Lithium-sulfur (Li-S) batteries hold great promise for the applications of high energy density storage. However, the performances of Li-S batteries are restricted by the low electrical conductivity of sulfur and shuttle effect of intermediate polysulfides. Moreover, the areal loading weights of sulfur in previous studies are usually low (around 1-3 mg cm-2) and thus cannot fulfill the requirement for practical deployment. Herein, we report that porous-shell vanadium nitride nanobubbles (VN-NBs) can serve as an efficient sulfur host in Li-S batteries, exhibiting remarkable electrochemical performances even with ultrahigh areal sulfur loading weights (5.4-6.8 mg cm-2). The large inner space of VN-NBs can afford a high sulfur content and accommodate the volume expansion, and the high electrical conductivity of VN-NBs ensures the effective utilization and fast redox kinetics of polysulfides. Moreover, VN-NBs present strong chemical affinity/adsorption with polysulfides and thus can efficiently suppress the shuttle effect via both capillary confinement and chemical binding, and promote the fast conversion of polysulfides. Benefiting from the above merits, the Li-S batteries based on sulfur-filled VN-NBs cathodes with 5.4 mg cm-2 sulfur exhibit impressively high areal/specific capacity (5.81 mAh cm-2), superior rate capability (632 mAh g-1 at 5.0 C), and long cycling stability.
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Despite high theoretical energy density, the practical deployment of lithium-sulfur (Li-S) batteries is still not implemented because of the severe capacity decay caused by polysulfide shuttling and the poor rate capability induced by low electrical conductivity of sulfur. Herein, we report a novel sulfur host material based on "sea urchin"-like cobalt nanoparticle embedded and nitrogen-doped carbon nanotube/nanopolyhedra (Co-NCNT/NP) superstructures for Li-S batteries. The hierarchical micromesopores in Co-NCNT/NP can allow efficient impregnation of sulfur and block diffusion of soluble polysulfides by physical confinement, and the incorporation of embedded Co nanoparticles and nitrogen doping (â¼4.6 at. %) can synergistically improve the adsorption of polysulfides, as evidenced by beaker cell tests. Moreover, the conductive networks of Co-NCNT/NP interconnected by nitrogen-doped carbon nanotubes (NCNTs) can facilitate electron transport and electrolyte infiltration. Therefore, the specific capacity, rate capability, and cycle stability of Li-S batteries are significantly enhanced. As a result, the Co-NCNT/NP based cathode (loaded with 80 wt % sulfur) delivers a high discharge capacity of 1240 mAh g-1 after 100 cycles at 0.1 C (based on the weight of sulfur), high rate capacity (755 mAh g-1 at 2.0 C), and ultralong cycling life (a very low capacity decay of 0.026% per cycle over 1500 cycles at 1.0 C). Remarkably, the composite cathode with high areal sulfur loading of 3.2 mg cm-2 shows high rate capacities and stable cycling performance over 200 cycles.
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Lithium-sulfur batteries (Li-S) have attracted soaring attention due to the particularly high energy density for advanced energy storage system. However, the practical application of Li-S batteries still faces multiple challenges, including the shuttle effect of intermediate polysulfides, the low conductivity of sulfur and the large volume variation of sulfur cathode. To overcome these issues, here we reported a self-templated approach to prepare interconnected carbon nanotubes inserted/wired hollow Co3S4 nanoboxes (CNTs/Co3S4-NBs) as an efficient sulfur host material. Originating from the combination of three-dimensional CNT conductive network and polar Co3S4-NBs, the obtained hybrid nanocomposite of CNTs/Co3S4-NBs can offer ultrahigh charge transfer properties, and efficiently restrain polysulfides in hollow Co3S4-NBs via the synergistic effect of structural confinement and chemical bonding. Benefiting from the above advantages, the S@CNTs/Co3S4-NBs cathode shows a significantly improved electrochemical performance in terms of high reversible capacity, good rate performance, and long-term cyclability. More remarkably, even at an elevated temperature (50 °C), it still exhibits high capacity retention and good rate capacity.
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The emergence of perovskite solar cells (PSCs) has generated enormous interest in the photovoltaic research community. Recently, cesium metal halides (CsMX3, M = Pb or Sn; X = I, Br, Cl or mixed halides) as a class of inorganic perovskites showed great promise for PSCs and other optoelectronic devices. However, CsMX3-based PSCs usually exhibit lower power conversion efficiencies (PCEs) than organic-inorganic hybrid PSCs, due to the unfavorable band gaps. Herein, a novel mixed-Pb/Sn mixed-halide inorganic perovskite, CsPb0.9Sn0.1IBr2, with a suitable band gap of 1.79 eV and an appropriate level of valence band maximum, was prepared in ambient atmosphere without a glovebox. After thoroughly eliminating labile organic components and noble metals, the all-inorganic PSCs based on CsPb0.9Sn0.1IBr2 and carbon counter electrodes exhibit a high open-circuit voltage of 1.26 V and a remarkable PCE up to 11.33%, which is record-breaking among the existing CsMX3-based PSCs. Moreover, the all-inorganic PSCs show good long-term stability and improved endurance against heat and moisture. This study indicates a feasible way to design inorganic halide perovskites through energy-band engineering for the construction of high-performance all-inorganic PSCs.
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The research field on perovskite solar cells (PSCs) is seeing frequent record breaking in the power conversion efficiency (PCE). However, organic-inorganic hybrid halide perovskites and organic additives in common hole-transport materials (HTMs) exhibit poor stability against moisture and heat. Here we report the successful fabrication of all-inorganic PSCs without any labile or expensive organic components. The entire fabrication process can be operated in ambient environment without humidity control (e.g., a glovebox). Even without encapsulation, the all-inorganic PSCs present no performance degradation in humid air (90-95% relative humidity, 25 °C) for over 3 months (2640 h) and can endure extreme temperatures (100 and -22 °C). Moreover, by elimination of expensive HTMs and noble-metal electrodes, the cost was significantly reduced. The highest PCE of the first-generation all-inorganic PSCs reached 6.7%. This study opens the door for next-generation PSCs with long-term stability under harsh conditions, making practical application of PSCs a real possibility.
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As fossil fuels continue to deplete, the development of sustainable and green energy sources has become crucial for human societal advancement. Among the various renewable energies, solar energy stands out as a promising substitute for conventional fossil fuels, offering widespread availability and a pollution-free solution. Solar cells, as devices that convert solar energy, are garnering significant focus. However, the intermittent nature of solar energy results in a high dependence on weather conditions of solar cells. Integrated solar cell-energy storage systems that integrate solar cells and energy storage devices may solve this problem by storing the generated electricity and managing the energy output. This review delves into the latest developments in integrated solar cell-energy storage systems, marrying various solar cells with either supercapacitors or batteries. It highlights their construction, material composition, and performance. Additionally, it discusses prevailing challenges and future possibilities, aiming to spark continued advancement and innovation in the sector.
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The remarkable flexibility and heightened sensitivity of flexible sensors have drawn significant attention, setting them apart from traditional sensor technology. Within this domain, hydrogels-3D crosslinked networks of hydrophilic polymers-emerge as a leading material for the new generation of flexible sensors, thanks to their unique material properties. These include structural versatility, which imparts traits like adhesiveness and self-healing capabilities. Traditional templating-based methods fall short of tailor-made applications in crafting flexible sensors. In contrast, 3D printing technology stands out with its superior fabrication precision, cost-effectiveness, and satisfactory production efficiency, making it a more suitable approach than templating-based strategies. This review spotlights the latest hydrogel-based flexible sensors developed through 3D printing. It begins by categorizing hydrogels and outlining various 3D-printing techniques. It then focuses on a range of flexible sensors-including those for strain, pressure, pH, temperature, and biosensors-detailing their fabrication methods and applications. Furthermore, it explores the sensing mechanisms and concludes with an analysis of existing challenges and prospects for future research breakthroughs in this field.
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Current technologies as correlation analysis, regression analysis and classification model, exhibited various limitations in the evaluation of soybean possessing potentials, including single, vague evaluation and failure of quantitative prediction, and thereby hindering more efficient and profitable soymilk industry. To solve this problem, 54 soybean cultivars and their corresponding soymilks were subjected to chemical, textural, and sensory analyses to obtain the soybean physicochemical nature (PN) and the soymilk profit and quality attribute (PQA) datasets. A deep-learning based model was established to quantitatively predict PQA data using PN data. Through 45 rounds of training with the stochastic gradient descent optimization, 9 remaining pairs of PN and PQA data were used for model validation. Results suggested that the overall prediction performance of the model showed significant improvements through iterative training, and the trained model eventually reached satisfying predictions (|relative error| ≤ 20%, standard deviation of relative error ≤ 40%) on 78% key soymilk PQAs. Future model training using big data may facilitate better prediction on soymilk odor qualities.
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Aprendizado Profundo , Glycine max , Leite de Soja , Leite de Soja/química , Glycine max/química , Glycine max/crescimento & desenvolvimento , Paladar , Odorantes/análise , Humanos , Manipulação de AlimentosRESUMO
Micro-supercapacitors (MSCs) have attracted significant attention for potential applications in miniaturized electronics due to their high power density, rapid charge/discharge rates, and extended lifespan. Despite the unique properties of low-dimensional nanomaterials, which hold tremendous potential for revolutionary applications, effectively integrating these attributes into MSCs presents several challenges. 3D printing is rapidly emerging as a key player in the fabrication of advanced energy storage devices. Its ability to design, prototype, and produce functional devices incorporating low-dimensional nanomaterials positions it as an influential technology. In this review, we delve into recent advancements and innovations in micro-supercapacitor manufacturing, with a specific focus on the incorporation of low-dimensional nanomaterials using direct ink writing (DIW) 3D printing techniques. We highlight the distinct advantages offered by low-dimensional nanomaterials, from quantum effects in 0D nanoparticles that result in high capacitance values to rapid electron and ion transport in 1D nanowires, as well as the extensive surface area and mechanical flexibility of 2D nanosheets. Additionally, we address the challenges encountered during the fabrication process, such as material viscosity, printing resolution, and seamless integration of active materials with current collectors. This review highlights the remarkable progress in the energy storage sector, demonstrating how the synergistic use of low-dimensional nanomaterials and 3D printing technologies not only overcomes existing limitations but also opens new avenues for the development and production of advanced micro-supercapacitors. The convergence of low-dimensional nanomaterials and DIW 3D printing heralds the advent of the next generation of energy storage devices, making a significant contribution to the field and laying the groundwork for future innovations.
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The synthesis of metal-organic framework (MOF) nanocomposites with high energy density and excellent mechanical strength is limited by the degree of lattice matching and crystal surface structure. In this study, dodecahedral ZIF-67 is synthesized uniformly on vanadium pentoxide nanowires. The influence of the coordination mode on the surface of ZIF-67 in ethanol is also investigated. Benefitting from the different coordination abilities of Ni2+ , Co2+ , and N atoms, spatially separated surface-active sites are created through metal-ion exchange. Furthermore, the incompatibility between the d8 electronic configuration of Ni2+ and the three-dimensional (3D) structure of ZIF-67 afforded the synthesis of hollow structures by controlling the amount of Ni doping. The formation of NiCo-MOF@CoOOH@V2 O5 nanocomposites is confirmed using X-ray absorption fine structure analysis. The high performance of the obtained composite is illustrated by fabricating a 3D-printed micro-supercapacitor, exhibiting a high area specific capacitance of 585 mF cm-2 and energy density of 159.23 µWh cm-2 (at power density = 0.34 mW cm-2 ). The solvent/coordination tuning strategy demonstrated in this study provides a new direction for the synthesis of high-performance nanomaterials for electrochemical energy storage applications.
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Recently, 2D transition metal carbide, nitride, and carbonitrides (MXenes) materials stand out in the field of tumor therapy, particularly in the construction of functional platforms for optimal antitumor therapy due to their high specific surface area, tunable performance, strong absorption of near-infrared light as well as preferable surface plasmon resonance effect. In this review, the progress of MXene-mediated antitumor therapy is summarized after appropriate modifications or integration procedures. The enhanced antitumor treatments directly performed by MXenes, the significant improving effect of MXenes on different antitumor therapies, as well as the MXene-mediated imaging-guided antitumor strategies are discussed in detail. Moreover, the existing challenges and future development directions of MXenes in tumor therapy are presented.
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Raios Infravermelhos , Neoplasias , Humanos , Nitritos , Ressonância de Plasmônio de Superfície , Neoplasias/tratamento farmacológicoRESUMO
Manganese dioxide (MnO2), as a cathode material for multivalent ion (such as Mg2+ and Al3+) storage, is investigated due to its high initial capacity. However, during multivalent ion insertion/extraction, the crystal structure of MnO2 partially collapses, leading to fast capacity decay in few charge/discharge cycles. Here, through pre-intercalating potassium-ion (K+) into δ-MnO2, we synthesize a potassium ion pre-intercalated MnO2, K0.21MnO2·0.31H2O (KMO), as a reliable cathode material for multivalent ion batteries. The as-prepared KMO exhibits a high reversible capacity of 185 mAh/g at 1 A/g, with considerable rate performance and improved cycling stability in 1 mol/L MgSO4 electrolyte. In addition, we observe that aluminum-ion (Al3+) can also insert into a KMO cathode. This work provides a valid method for modification of manganese-based oxides for aqueous multivalent ion batteries.