Formulating N-Doped Carbon Hollow Nanospheres with Highly Accessible Through-Pores to Isolate Fe Single-Atoms for Efficient Oxygen Reduction.

It is challenging yet promising to design highly accessible N-doped carbon skeletons to fully expose the active sites inside single-atom catalysts. Herein, mesoporous N-doped carbon hollow spheres with regulatable through-pore size can be formulated by a simple sequential synthesis procedure, in which the condensed SiO2 is acted as removable dual-templates to produce both hollow interiors and through-pores, meanwhile, the co-condensed polydopamine shell is served as N-doped carbon precursor. After that, Fe─N─C hollow spheres (HSs) with highly accessible active sites can be obtained after rationally implanting Fe single-atoms. Microstructural analysis and X-ray absorption fine structure analysis reveal that high-density Fe─N4 active sites together with tiny Fe clusters are uniformly distributed on the mesoporous carbon skeleton with abundant through-pores. Benefitted from the highly accessible Fe─N4 active sites arising from the unique through-pore architecture, the Fe─N─C HSs demonstrate excellent oxygen reduction reaction (ORR) performance in alkaline media with a half-wave potential up to 0.90 V versus RHE and remarkable stability, both exceeding the commercial Pt/C. When employing Fe─N─C HSs as the air-cathode catalysts, the assembled Zn-air batteries deliver a high peak power density of 204 mW cm-2 and stable discharging voltage plateau over 140 h.

TiN as Radical Scavenger in Fe─N─C Aerogel Oxygen Reduction Catalyst for Durable Fuel Cell.

Fe─N─C is the most promising alternative to platinum-based catalysts to lower the cost of proton-exchange-membrane fuel cell (PEMFC). However, the deficient durability of Fe─N─C has hindered their application. Herein, a TiN-doped Fe─N─C (Fe─N─C/TiN) is elaborately synthesized via the sol-gel method for the oxygen-reduction reaction (ORR) in PEMFC. The interpenetrating network composed by Fe─N─C and TiN can simultaneously eliminate the free radical intermediates while maintaining the high ORR activity. As a result, the H2O2 yields of Fe─N─C/TiN are suppressed below 4%, ≈4 times lower than the Fe─N─C, and the half-wave potential only lost 15 mV after 30 kilo-cycle accelerated durability test (ADT). In a H2─O2 fuel cell assembled with Fe─N─C/TiN, it presents 980 mA cm-2 current density at 0.6 V, 880 mW cm-2 peak power density, and only 17 mV voltage loss at 0.80 A cm-2 after 10 kilo-cycle ADT. The experiment and calculation results prove that the TiN has a strong adsorption interaction for the free radical intermediates (such as *OH, *OOH, etc.), and the radicals are scavenged subsequently. The rational integration of Fe single-atom, TiN radical scavenger, and highly porous network adequately utilize the intrinsic advantages of composite structure, enabling a durable and active Pt-metal-free catalyst for PEMFC.

Construction of an Axial Charge Transfer Channel Between Single-Atom Fe Sites and Nitrogen-Doped Carbon Supports for Boosting Oxygen Reduction.

The introduction of axial-coordinated heteroatoms in Fe─N─C single-atom catalysts enables the significant enhancement of their oxygen reduction reaction (ORR) performance. However, the interaction relationship between the axial-coordinated heteroatoms and their carbon supports is still unclear. In this work, a gas phase surface treatment method is proposed to prepare a series of X─Fe─N─C (X = O, P, and S) single-atom catalysts with axial X-coordination on graphitic-N-rich carbon supports. Synchrotron-based X-ray absorption near-edge structure spectra and X-ray photoelectron spectroscopy indicate the formation of an axial charge transfer channel between the graphitic-N-rich carbon supports and single-atom Fe sites by axial O atoms in O─Fe─N─C. As a result, the O─Fe─N─C exhibits excellent ORR performance with a half-wave potential of 0.905 V versus RHE and a high specific capacity of 884 mAh g-1 for zinc-air battery, which is superior to other X─Fe─N─C catalysts without axial charge transfer and the commercial Pt/C catalyst. This work not only demonstrates a general synthesis strategy for the preparation of single-atom catalysts with axial-coordinated heteroatoms, but also presents insights into the interaction between single-atom active sites and doped carbon supports.

Numerical evaluation of internal femur osteosynthesis based on a biomechanical model of the loading in the proximal equine hindlimb.

Femoral fractures are often considered lethal for adult horses because femur osteosynthesis is still a surgical challenge. For equine femur osteosynthesis, primary stability is essential, but the detailed physiological forces occurring in the hindlimb are largely unknown. The objective of this study was to create a numerical testing environment to evaluate equine femur osteosynthesis based on physiological conditions. The study was designed as a finite element analysis (FEA) of the femur using a musculoskeletal model of the loading situation in stance. Relevant forces were determined in the musculoskeletal model via optimization. The treatment of four different fracture types with an intramedullary nail was investigated in FEA with loading conditions derived from the model. The analyzed diaphyseal fracture types were a transverse (TR) fracture, two oblique fractures in different orientations (OB-ML: medial-lateral and OB-AP: anterior-posterior) and a "gap" fracture (GAP) without contact between the fragments. For the native femur, the most relevant areas of increased stress were located distally to the femoral head and proximally to the caudal side of the condyles. For all fracture types, the highest stresses in the implant material were present in the fracture-adjacent screws. Maximum compressive (-348 MPa) and tensile stress (197 MPa) were found for the GAP fracture, but material strength was not exceeded. The mathematical model was able to predict a load distribution in the femur of the standing horse and was used to assess the performance of internal fixation devices via FEA. The analyzed intramedullary nail and screws showed sufficient stability for all fracture types.

Biomechanical changes of oblique lumbar interbody fusion with different fixation techniques in degenerative spondylolisthesis lumbar spine: a finite element analysis.

OBJECTIVE: There is a dearth of comprehensive research on the stability of the spinal biomechanical structure when combining Oblique Lumbar Interbody Fusion (OLIF) with internal fixation methods. Hence, we have devised this experiment to meticulously examine and analyze the biomechanical changes that arise from combining OLIF surgery with different internal fixation techniques in patients diagnosed with degenerative lumbar spondylolisthesis. METHODS: Seven validated finite element models were reconstructed based on computed tomography scan images of the L3-L5 segment. These models included the intact model, a stand-alone (S-A) OLIF model, a lateral screw rod (LSR) OLIF model, a bilateral pedicle screw (BPS) OLIF model, an unilateral pedicle screw (UPS) OLIF model, a bilateral CBT (BCBT) OLIF model, and an unilateral CBT(UCBT) OLIF model. The range of motion (ROM), as well as stress levels in the cage, L4 lower endplate, L5 upper endplate, and fixation constructs were assessed across these different model configurations. RESULTS: S-A model had the highest average ROM of six motion modes, followed by LSR, UPS, UCBT, BPS and BCBT. The BCBT model had a relatively lower cage stress than the others. The maximum peak von Mises stress of the fixation constructs was found in the LSR model. The maximum peak von Mises stress of L4 lower endplate was found in the S-A model. The peak von Mises stress on the L4 lower endplate of the rest surgical models showed no significant difference. The maximum peak von Mises stress of the L5 upper endplate was found in the S-A model. The minimum peak von Mises stress of the L5 upper endplate was found in the BCBT model. No significant difference was found for the peak von Mises stress of the L5 upper endplate among LSR, BPS, UPS and UCBT models. CONCLUSION: Among the six different fixation techniques, BCBT exhibited superior biomechanical stability and minimal stress on the cage-endplate interface. It was followed by BPS, UCBT, UPS, and LSR in terms of effectiveness. Conversely, S-A OLIF demonstrated the least stability and resulted in increased stress on both the cage and endplates. Combining OLIF with BCBT fixation technique enhanced biomechanical stability compared to BPS and presented as a less invasive alternative treatment for patients with degenerative lumbar spondylolisthesis.

Biomechanical impact of different isthmus positions in mandibular first molar root canals: a finite element analysis.

OBJECTIVE: This study used image-based finite element analysis (FEA) to assess the biomechanical changes in mandibular first molars resulting from alterations in the position of the root canal isthmus. METHODS: A healthy mandibular first molar, characterized by two intact root canals and a cavity-free surface, was selected as the subject. A three-dimensional model for the molar was established using scanned images of the patient's mandibular teeth. Subsequently, four distinct finite element models were created, each representing varied root canal morphologies: non-isthmus (Group A), isthmus located at the upper 1/3 of the root (Group B), middle 1/3 of the root (Group C), and lower 1/3 of the root (Group D). A static load of 200 N was applied along the tooth's longitudinal axis on the occlusal surface to simulate regular chewing forces. The biomechanical assessment was conducted regarding the mechanical stress profile within the root dentin. The equivalent stress (Von Mises stress) was used to assess the biomechanical features of mandibular teeth under mechanical loading. RESULTS: In Group A (without an isthmus), the maximum stress was 22.2 MPa, while experimental groups with an isthmus exhibited higher stresses, reaching up to 29.4 MPa. All maximum stresses were concentrated near the apical foramen. The presence of the isthmus modified the stress distribution in the dentin wall of the tooth canal. Notably, dentin stresses at specific locations demonstrated differences: at 8 mm from the root tip, Group B: 13.6 MPa vs. Group A: 11.4 MPa; at 3 mm from the root tip, Group C: 14.2 MPa vs. Group A: 4.5 MPa; at 1 mm from the root tip, Group D: 25.1 MPa vs. Group A: 10.3 MPa. The maximum stress in the root canal dentin within the isthmus region was located either at the top or bottom of the isthmus. CONCLUSION: A root canal isthmus modifies the stress profile within the dentin. The maximum stress occurs near the apical foramen and significantly increases when the isthmus is located closer to the apical foramina.

Integration of Finite Element Analysis and Laboratory Analysis on 3D Models for Methodology Calibration.

To better address mechanical behavior, it is necessary to make use of modern tools through which it is possible to run predictions, simulate scenarios, and optimize decisions. sources integration. This will increase the capability of detecting material modifications that forerun damage and/or to forecast the stage in the future when very likely fatigue is initiating and propagating cracks. Early warning outcomes obtained by the synergetic implementation of NDE-based protocols for studying mechanical and fatigue and fracture behavior will enhance the preparedness toward economically sustainable future damage control scenarios. Specifically, these early warning outcomes will be developed in the form of retopologized models to be used coupled with FEA. This paper presents the first stage of calibration and the combination of a system of different sensors (photogrammetry, laser scanning and strain gages) for the creation of volumetric models suitable for the prediction of failure of FEA software. The test objects were two components of car suspension to which strain gauges were attached to measure its deformation under cyclic loading. The calibration of the methodology was carried out using models obtained from photogrammetry and experimental strain gauge measurements.

Thermalization of Mesh Reinforced Ultra-Thin Al-Coated Plastic Films: A Parametric Study Applied to the Athena X-IFU Instrument.

The X-ray Integral Field Unit (X-IFU) is one of the two focal plane detectors of Athena, a large-class high energy astrophysics space mission approved by ESA in the Cosmic Vision 2015-2025 Science Program. The X-IFU consists of a large array of transition edge sensor micro-calorimeters that operate at ~100 mK inside a sophisticated cryostat. To prevent molecular contamination and to minimize photon shot noise on the sensitive X-IFU cryogenic detector array, a set of thermal filters (THFs) operating at different temperatures are needed. Since contamination already occurs below 300 K, the outer and more exposed THF must be kept at a higher temperature. To meet the low energy effective area requirements, the THFs are to be made of a thin polyimide film (45 nm) coated in aluminum (30 nm) and supported by a metallic mesh. Due to the small thickness and the low thermal conductance of the material, the membranes are prone to developing a radial temperature gradient due to radiative coupling with the environment. Considering the fragility of the membrane and the high reflectivity in IR energy domain, temperature measurements are difficult. In this work, a parametric numerical study is performed to retrieve the radial temperature profile of the larger and outer THF of the Athena X-IFU using a Finite Element Model approach. The effects on the radial temperature profile of different design parameters and boundary conditions are considered: (i) the mesh design and material, (ii) the plating material, (iii) the addition of a thick Y-cross applied over the mesh, (iv) an active heating heat flux injected on the center and (v) a Joule heating of the mesh. The outcomes of this study have guided the choice of the baseline strategy for the heating of the Athena X-IFU THFs, fulfilling the stringent thermal specifications of the instrument.

Sensor-Enhanced Thick Laminated Composite Beams: Manufacturing, Testing, and Numerical Analysis.

This study investigates the manufacturing, testing, and analysis of ultra-thick laminated polymer matrix composite (PMC) beams with the aim of developing high-performance PMC leaf springs for automotive applications. An innovative aspect of this study is the integration of Fiber Bragg Grating (FBG) sensors and thermocouples (TCs) to monitor residual strain and exothermic reactions in composite structures during curing and post-curing manufacturing cycles. Additionally, the Calibration Coefficients (CCs) are calculated using Strain Gauge measurement results under static three-point bending tests. A major part of the study focuses on developing a properly correlated Finite Element (FE) model with large deflection (LD) effects using geometrical nonlinear analysis (GNA) to understand the deformation behavior of ultra thick composite beam (ComBeam) samples, advancing the understanding of large deformation behavior and filling critical research gaps in composite materials. This model will help assess the internal strain distribution, which is verified by correlating data from FBG sensors, Strain Gauges (SGs), and FE analysis. In addition, this research focuses on the application of FBG sensors in structural health monitoring (SHM) in fatigue tests under three-point bending with the support of load-deflection sensors: a new approach for composites at this scale. This study revealed that the fatigue performance of ComBeam samples drastically decreased with increasing displacement ranges, even at the same maximum level, underscoring the potential of FBG sensors to enhance SHM capabilities linked to smart maintenance.

A General "In Situ Etch-Adsorption-Phosphatization" Strategy for the Fabrication of Metal Phosphides/Hollow Carbon Composite for High Performance Liquid/Flexible Zn-Air Batteries.

Benefiting from the admirable energy density (1086 Wh kg-1 ), overwhelming security, and low environmental impact, rechargeable zinc-air batteries (ZABs) are deemed to be attractive candidates for lithium-ion batteries. The exploration of novel oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) bifunctional catalysts is the key to promoting the development of zinc-air batteries. Transitional metal phosphides (TMPs) especially Fe-based TMPs are deemed to be a rational type of catalyst, however, their catalytic performance still needs to be further improved. Considering Fe (heme) and Cu (copper terminal oxidases) are nature's options for ORR catalysis in many forms of life from bacteria to humans. Herein, a general "in situ etch-adsorption-phosphatization" strategy is designed for the fabrication of hollow FeP/Fe2 P/Cu3 P-N, P codoped carbon (FeP/Cu3 P-NPC) catalyst as the cathode of liquid and flexible ZABs. The liquid ZABs manifest a high peak power density of 158.5 mW cm-2 and outstanding long-term cycling performance (≈1100 cycles at 2 mA cm-2 ). Similarly, the flexible ZABs deliver superior cycling stability of 81 h at 2 mA cm-2 without bending and 26 h with different bending angles.

Radial HR-pQCT and Finite Element Analysis in HPP Patients are Superior in Identifying Susceptibility to Fracture-Associated Skeletal Affections Compared to DXA and Laboratory Tests.

Hypophosphatasia (HPP) is an inborn disease that causes a rare form of osteomalacia, a mineralization disorder affecting mineralized tissues. Identification of patients at high risk for fractures or other skeletal manifestations (such as insufficiency fractures or excessive bone marrow edema) by bone densitometry and laboratory tests remains clinically challenging. Therefore, we examined two cohorts of patients with variants in the ALPL gene grouped by bone manifestations. These groups were compared by means of bone microarchitecture using high-resolution peripheral quantitative computed tomography (HR-pQCT) and simulated mechanical performance utilizing finite element analysis (FEA). Whereas the incidence of skeletal manifestations among the patients could not be determined by dual energy X-ray absorptiometry (DXA) or laboratory assessment, HR-pQCT evaluation showed a distinct pattern of HPP patients with such manifestations. Specifically, these patients had a pronounced loss of trabecular bone mineral density, increased trabecular spacing, and decreased ultimate force at the distal radius. Interestingly, the derived results indicate that the non-weight-bearing radius is superior to the weight-bearing tibia in identifying deteriorated skeletal patterns. Overall, the assessment by HR-pQCT appears to be of high clinical relevance due to the improved identification of HPP patients with an increased risk for fractures or other skeletal manifestations, especially at the distal radius.

Investigation of flexural behaviour of composite rebars for concrete reinforcement with experimental, numerical and machine learning approaches.

Three different types (with glass, basalt and hybrid fibres) of composite rebars manufactured using the pultrusion process were loaded in four-point bending tests. All tests were carried out with acoustic emission sensors to better understand the mechanisms of damage. The data obtained were investigated using standard parameter analysis and also using unsupervised machine learning techniques called K-means. It was found that the best number of clusters is four or five. The numerical model using the finite-element method was calibrated on the basis of the experimental data. Further research will focus on numerical modelling of flexural behaviour of concrete beams reinforced with the presented composite rebars. The presented paper focuses on the characterization of the mechanical properties of composite rebars using a micromechanical approach, as well as analysis of progression damage processes appearing under flexural loading, using different perspectives provided by techniques such as acoustic emission analysis with machine learning-based clustering and numerical simulations. The presented research confirms that the proposed experimental-numerical approach can be applied in order to describe the flexural behaviour of Fibre Reinforcement Polymer (FRP) rods, which is relevant for investigating more complex cases of FRP concrete structures. This article is part of the theme issue 'Physics-informed machine learning and its structural integrity applications (Part 1)'.

Factors influencing cage subsidence in anterior cervical corpectomy and discectomy: a systematic review.

PURPOSE: Various factors have been examined in relation to cage subsidence risk, including cage material, cage geometry, bone mineral density, device type, surgical level, bone graft, and patient age. The present study aims to compare and synthesize the literature of both clinical and biomechanical studies to evaluate and present the factors associated with cage subsidence. METHODS: A comprehensive search of the literature from January 2003 to December 2021 was conducted using the PubMed and ScienceDirect databases by following the Preferred Reporting Items for Systematic Reviews and Meta-Analyses guidelines. Following the screening for inclusion and exclusion criteria, a total of 49 clinical studies were included. Correlations between clinical and biomechanical studies are also discussed. RESULTS: Patients treated with the cage and plate combination had a lower subsidence rate than patients with the stand-alone cage. Overall, Polyetheretherketone material was shown to have a lower subsidence rate than titanium and other materials. The subsidence rate was also higher when the surgery was performed at levels C5-C7 than at levels C2-C5. No significant correlation was found between age and cage subsidence clinically. CONCLUSIONS: Cage subsidence increases the stress on the anterior fixation system and may cause biomechanical instability. Severe cage subsidence decreases the Cobb angle and intervertebral height, which may cause destabilization of the implant system, such as screw/plate loosening or breakage of the screw/plate. Various factors have been shown to influence the risk of cage subsidence. Examining clinical research alongside biomechanical studies offers a more comprehensive understanding of the subject.

Comprehensive morphomechanical analysis of brain aneurysms.

OBJECTIVE: Brain aneurysms comprise different compartments that undergo unique biological processes. A detailed multimodal analysis incorporating 3D aneurysm wall enhancement (AWE), computational fluid dynamics (CFD), and finite element analysis (FEA) data can provide insights into the aneurysm wall biology. METHODS: Unruptured aneurysms were prospectively imaged with 7 T high-resolution MRI (HR-MRI). 3D AWE color maps of the entire aneurysm wall were generated and co-registered with contour plots of morphomechanical parameters derived from CFD and FEA. A multimodal analysis of the entire aneurysm was performed using 3D circumferential AWE (3D-CAWE), wall tension (WT), time-averaged wall shear stress (TAWSS), wall shear stress gradient (WSSG), and oscillatory shear index (OSI). A detailed compartmental analysis of each aneurysm's dome, bleb, and neck was also performed. RESULTS: Twenty-six aneurysms were analyzed. 3D-CAWE + aneurysms had higher WT (p = 0.03) and higher TAWSS (p = 0.045) than 3D-CAWE- aneurysms. WT, TAWSS, and WSSG were lower in areas of focal AWE in the aneurysm dome compared to the neck (p = 0.009, p = 0.049, and p = 0.040, respectively), whereas OSI was higher in areas of focal AWE compared to the neck (p = 0.020). When compared to areas of no AWE of the aneurysm sac (AWE = 0.92 vs. 0.49, p = 0.001), blebs exhibited lower WT (1.6 vs. 2.45, p = 0.010), lower TAWSS (2.6 vs. 6.34), lower OSI (0.0007 vs. 0.0010), and lower WSSG (2900 vs. 5306). Fusiform aneurysms had a higher 3D-CAWE and WT than saccular aneurysms (p = 0.046 and p = 0.003, respectively). CONCLUSIONS: Areas of focal high AWE in the sac and blebs are associated with low wall tension, low wall shear stress, and low flow conditions (TAWSS and WSSG). Conversely, the neck had average AWE, high wall tension, high wall shear stress, and high flow conditions. The aneurysm dome and the aneurysm neck have different morphomechanical environments, with increased mechanical load at the neck.

Survival dependence of 3D-printed temporary materials on the filler content.

AIM: The aim of the present study was the evaluation of the in vitro performance and fracture force of 3D-printed anterior implant-supported temporary partial dentures (TPDs) with different filler content. MATERIALS AND METHODS: Identical anterior resin-based TPDs (tooth sites 11 to 13; n = eight per material) were 3D printed from methacrylate resins with different filler content. A cartridge polymethyl methacrylate (PMMA) material was used as a reference. After temporary cementation, combined thermal cycling and mechanical loading (TCML) was performed on all the restorations to mimic clinical application. Behavior during TCML and fracture force was determined, and failures were analyzed. Data were statistically investigated (Kolmogorov-Smirnov test, one-way ANOVA; post hoc Bonferroni, Kaplan-Meier survival; α = 0.05). RESULTS: Failure during TCML varied between three failures and total failure during loading time. Mean survival time varied between 93 ± 206 x 103 cycles and 329 ± 84 x 103 cycles. Significantly different survival cycles between the individual materials could be determined (Mantel Cox log-rank test: chi-square: 21,861; degrees of freedom (df) = 4, P < 0.001). A correlation between filler level and survival cycles could be found (Pearson: 0.186, P = 0.065). Fracture values of the surviving TPDs varied between 499 and 835 N. Failures were characterized by fracture of the connector (n = 24) followed by fractures at the abutment (n = 10). CONCLUSIONS: TDPs showed different filler-dependent survival. Individual 3D-printed materials provided comparable or even better performance than a standard cartridge system and might be sufficient for temporary application of at least half a year.

Vacuum joints of CuCrZr alloy for high-heat-load photon absorber.

A photon absorber, as a critical component of a synchrotron front-end, is mainly used to handle high-heat-load synchrotron radiation. It is mostly made of dispersion strengthened copper or CuCrZr which can retain high performance at elevated temperatures. Joining processes for vacuum, including tungsten inert gas welding (TIG) and electron beam welding (EBW), are novel ways to make a long photon absorber from two short ones and reduce power density. The mechanical properties of TIG joints and EBW joints of CuCrZr to the same material are obtained by tensile tests at 20°C, 100°C, 200°C, 300°C and 400°C. Testing results indicate that the tensile strength and yield strength of both vacuum joints decline as temperature increases. Compared with TIG joints, EBW joints have higher strength, better ductility and a more stable performance. An engineering conservative acceptance criteria of the vacuum joints is created by the polynomial fitting method. A novel welded photon absorber with a total length of 600 mm has been successfully designed and manufactured. Finite-element analysis by ANSYS shows that the maximum temperature, equivalent stress and strain are only 31.5%, 36.2% and 1.3%, respectively, of the corresponding thresholds. The welded photon absorbers with EBW joints will be applicable in the highest-heat-load front-end in the Shanghai Synchrotron Radiation Facility Phase-II beamline project.

High-resolution X-ray tomographic workflow to investigate the stress distribution in vitreous enamel steels.

Vitreous enamel steels (VES) are a class of metal-ceramic composite materials realised with a low carbon steel basement coated by an enamel layer. During the firing phase to adhere the enamel to the metal, several gas bubbles remain entrapped inside the enamel volume modifying its internal structure. In this work high-resolution X-ray computed tomography (micro-CT) was used to investigate these composite materials. The micro-CT reconstructions enabled a detailed investigation of VES minimising the metal artefacts. The tomograms were used to develop finite element models (FEM) of VES by means of a representative volume element (RVE) to evaluate the thermal residual stresses caused by the manufacturing process, as well as the effect of the 3D bubbles distribution on the internal stress patterns after the thermic gradient. The promising results from this study have the potential to inform further research on such composite materials by optimising manufacturing processes for targeted applications.

Vitreous enamel steels are a particular class of composite materials composed by a low carbon steel basement coated by a vitreous enamel layer. Throughout the firing process applied to fix the enamel on the steel substrate, several gas bubbles remain entrapped inside the internal volume of the enamel modifying its internal microstructure. The presence of these bubbles substantially modifies the internal mechanical state of the structure developing residual stresses both among the bubbles and between the enamel-metal surface. However, to date no methods are still available to properly investigate the 3D bubbles morphology, distribution and stress patterns inside these materials. For this reason, in the present study we developed for the first time a high-resolution X-ray computed tomography (micro-CT) protocol able to investigate the vitreous enamel steels full field structure and numerically study their mechanics when the thermal gradient is applied. The micro-CT scans reconstructions allowed the visualisation of the enamel coating structure minimising metal artefacts. Moreover, the scans were postprocessed developing unpreceded 3D reconstructions with which the distribution, the volume and the mean diameter of the bubbles were analysed and defined. Subsequently, full field finite element computational models able to evaluate the thermal residual stresses produced inside the enamel volume were developed. They permitted to investigate the effect of the bubbles distribution on the internal residual stress patterns due to the thermal gradient generated throughout the cooling phase. The promising results from this study have the potential to inform further research on such composite materials by optimising manufacturing processes for targeted applications.

The effect of talus osteochondral defects of different area size on ankle joint stability: a finite element analysis.

BACKGROUND: Osteochondral lesion of the talus (OLT) is one of the most common ankle injuries, which will lead to biomechanical changes in the ankle joint and ultimately affect ankle function. Finite element analysis (FEA) is used to clarify the effect of talus osteochondral defects on the stability of the ankle joint at different depths. However, no research has been conducted on talus osteochondral defect areas that require prompt intervention. In this research, FEA was used to simulate the effect of the area size of talus osteochondral defect on the stress and stability of the ankle joint under a specific depth defect. METHODS: Different area sizes (normal, 2 mm* 2 mm, 4 mm* 4 mm, 6 mm* 6 mm, 8 mm* 8 mm, 10 mm* 10 mm, and 12 mm* 12 mm) of the three-dimensional finite element model of osteochondral defects were established. The model was used to simulate and calculate joint stress and displacement of the articular surface of the distal tibia and the proximal talus when the ankle joint was in the heel-strike, midstance, and push-off phases. RESULTS: When OLT occurred, the contact pressure of the articular surface, the equivalent stress of the proximal talus, the tibial cartilage, and the talus cartilage did not change significantly with an increase in the size of the osteochondral defect area when the heel-strike phase was below 6 mm * 6 mm. Gradual increases started at 6 mm * 6 mm in the midstance and push-off phases. Maximum changes were reached when the defect area size was 12 mm * 12 mm. The same patterns were observed in the talus displacement. CONCLUSIONS: The effect of the defect area of the ankle talus cartilage on the ankle biomechanics is evident in the midstance and push-off phases. When the size of the defect reaches 6 mm * 6 mm, the most apparent change in the stability of the ankle joint occurs, and the effect does not increase linearly with the increase in the size of the defect.

3D Reality-Based Survey and Retopology for Structural Analysis of Cultural Heritage.

Cultural heritage's structural changes and damages can influence the mechanical behaviour of artefacts and buildings. The use of finite element methods (FEM) for mechanical analysis is largely used in modelling stress behaviour. The workflow involves the use of CAD 3D models and the use of non-uniform rational B-spline (NURBS) surfaces. For cultural heritage objects, altered by the time elapsed since their creation, the representation created with the CAD model may introduce an extreme level of approximation, leading to wrong simulation results. The focus of this work is to present an alternative method intending to generate the most accurate 3D representation of a real artefact from highly accurate 3D reality-based models, simplifying the original models to make them suitable for finite element analysis (FEA) software. The approach proposed, and tested on three different case studies, was based on the intelligent use of retopology procedures to create a simplified model to be converted to a mathematical one made by NURBS surfaces, which is also suitable for being processed by volumetric meshes typically embedded in standard FEM packages. This allowed us to obtain FEA results that were closer to the actual mechanical behaviour of the analysed heritage asset.

Design Optimization of Sensitivity-Enhanced Structure for Fiber Bragg Grating Acoustic Emission Sensor Based on Additive Manufacturing.

A four-loop shaped structure of fiber Bragg grating (FBG) acoustic emission (AE) sensor based on additive manufacturing (AM) technology is proposed in the letter. The finite element analysis (FEA) method was used to model and analyze the sensor structure. We aimed at improving the sensitivity, the static load analysis, and the dynamic response analysis of the normal FBG acoustic emission sensor and the FBG AE sensor with improved structure parameters. We constructed the FBG AE sensor experimental system based on a narrowband laser demodulation method and test on real acoustic emission signals. The results demonstrated that the response sensitivity of the FBG acoustic emission sensor was 1.47 times higher than the sensitivity of the normal FBG sensor. The sensitivity coefficient of PLA-AE-FBG2 sensor was 3.057, and that of PLA-AE-FBG1 was 2.0702. Through structural design and parameter optimization, the sensitivity and stability of the FBG AE sensor are improved. The four-loop shaped sensor is more suitable for the health monitoring in fields such as aero-engine blade, micro-crack of structure, and crack growth in bonded joints. While ensuring the sensing characteristics, sensitivity, and stability of the four-loop shaped sensor have been enhanced. It is possible to apply the FBG AE sensor in some complex engineering environments.