Enantioselective synthesis of axially chiral biaryls by the Pd-catalyzed Suzuki-Miyaura reaction: substrate scope and quantum mechanical investigations.

Shen, Xiaoqiang; Jones, Gavin O; Watson, Donald A; Bhayana, Brijesh; Buchwald, Stephen L

Shen, Xiaoqiang; Jones, Gavin O; Watson, Donald A; Bhayana, Brijesh; Buchwald, Stephen L.

Affiliation

Shen X; Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA.

J Am Chem Soc ; 132(32): 11278-87, 2010 Aug 18.

Article in En | MEDLINE | ID: mdl-20698695

Subject(s)

Hydrocarbons, Aromatic/chemistry; Palladium/chemistry; Quantum Theory; Catalysis; Hydrogen Bonding; Ligands; Models, Molecular; Molecular Conformation; Stereoisomerism; Substrate Specificity; Thermodynamics

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Full text: 1 Database: MEDLINE Main subject: Palladium / Quantum Theory / Hydrocarbons, Aromatic Language: En Journal: J Am Chem Soc Year: 2010 Type: Article Affiliation country: United States

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