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Bis{S-benzyl 3-[(6-methyl-pyridin-2-yl)methyl-idene]dithio-carbazato}nickel(II).
Ravoof, Thahira Begum S A; Omar, Siti Aminah; Mohamed Tahir, Mohamed Ibrahim; Crouse, Karen A.
Affiliation
  • Ravoof TB; Department of Chemistry, Faculty of Science, Universiti Putra Malaysia, 43400 UPM, Serdang, Selangor, Malaysia.
Acta Crystallogr Sect E Struct Rep Online ; 68(Pt 5): m664, 2012 May 01.
Article in En | MEDLINE | ID: mdl-22590148
The asymmetric unit of the title compound, [Ni(C(15)H(14)N(3)S(2))(2)], consists of two independent mol-ecules with similar configurations. Each Ni(2+) cation is coordinated in a cis-mode by two tridentate N,N',S-chelating Schiff base ligands, creating a distorted octa-hedron [the smallest angle being 77.57 (7)° and the widest being 168.97 (7)° for one mol-ecule, and 78.04 (7) and 167.55 (7)° for the second mol-ecule]. The dihedral angle between the mean coordination planes of the two ligands is 86.76 (7)° for one and 89.99 (7)° for the second mol-ecule. π-π inter-actions between neighbouring pyridine rings with plane-to-plane distances of 3.540 (1) and 3.704 (1) Šare observed.

Full text: 1 Database: MEDLINE Language: En Journal: Acta Crystallogr Sect E Struct Rep Online Year: 2012 Type: Article Affiliation country: Malaysia

Full text: 1 Database: MEDLINE Language: En Journal: Acta Crystallogr Sect E Struct Rep Online Year: 2012 Type: Article Affiliation country: Malaysia