Bis{S-benzyl 3-[(6-methyl-pyridin-2-yl)methyl-idene]dithio-carbazato}nickel(II).
Acta Crystallogr Sect E Struct Rep Online
; 68(Pt 5): m664, 2012 May 01.
Article
in En
| MEDLINE
| ID: mdl-22590148
The asymmetric unit of the title compound, [Ni(C(15)H(14)N(3)S(2))(2)], consists of two independent mol-ecules with similar configurations. Each Ni(2+) cation is coordinated in a cis-mode by two tridentate N,N',S-chelating Schiff base ligands, creating a distorted octa-hedron [the smallest angle being 77.57â
(7)° and the widest being 168.97â
(7)° for one mol-ecule, and 78.04â
(7) and 167.55â
(7)° for the second mol-ecule]. The dihedral angle between the mean coordination planes of the two ligands is 86.76â
(7)° for one and 89.99â
(7)° for the second mol-ecule. π-π inter-actions between neighbouring pyridine rings with plane-to-plane distances of 3.540â
(1) and 3.704â
(1)â
Å are observed.
Full text:
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Database:
MEDLINE
Language:
En
Journal:
Acta Crystallogr Sect E Struct Rep Online
Year:
2012
Type:
Article
Affiliation country:
Malaysia