Theoretical Investigation of the Photoexcited NO2 +H2 O reaction at the Air-Water Interface and Its Atmospheric Implications.
Chemistry
; 25(61): 13899-13904, 2019 Nov 04.
Article
in En
| MEDLINE
| ID: mdl-31241211
ABSTRACT
The atmospheric role of photochemical processes involving NO2 beyond its dissociation limit (398â
nm) is controversial. Recent experiments have confirmed that excited NO2 * beyond 420â
nm reacts with water according to NO2 * +H2 OâHONO+OH. However, the estimated kinetic constant for this process in the gas phase is quite small (k≈10-15 -3.4×10-14 â
cm3 molecule-1 s-1 ) suggesting minor atmospheric implications of the formed radicals. In this work, ab initio molecular dynamics simulations of NO2 adsorbed at the air-water interface reveal that the OH production rate increases by about 2 orders of magnitude with respect to gas phase, attaining ozone reference values for NO2 concentrations corresponding to slightly polluted rural areas. This finding substantiates the argument that chemistry on clouds can be an additional source of OH radicals in the troposphere and suggests directions for future laboratory experimental studies.
Full text:
1
Database:
MEDLINE
Language:
En
Journal:
Chemistry
Journal subject:
QUIMICA
Year:
2019
Type:
Article
Affiliation country:
France