Rational Assembly of Metallophilic Gold(I)-Lead(II) and Gold(I)-Gold(I) Puzzle Pieces.
Angew Chem Int Ed Engl
; 60(2): 640-644, 2021 Jan 11.
Article
in En
| MEDLINE
| ID: mdl-33006214
The assembly of two different building blocks, [{Au(C6 F5 )2 }{PbCl(terpy)}] (terpy=2,2':6':2''-terpyridine) and [{Au(C6 F5 )2 }2 {Pb(terpy)}]n , acting as terminal or central pieces, respectively, gives rise to a decanuclear complex built via metallophilic and π-stacking interactions in which the number of AuI â
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AuI and AuI â
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PbII contacts is finely controlled.
Full text:
1
Database:
MEDLINE
Language:
En
Journal:
Angew Chem Int Ed Engl
Year:
2021
Type:
Article
Affiliation country:
Spain