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Scalable Electrocatalytic Intermolecular Acylcyanation and Aminocyanation of Alkenes.
Kong, Xianqiang; Chen, Xiaohui; Chen, Yiyi; Cao, Zhong-Yan.
Affiliation
  • Kong X; School of Chemical Engineering and Materials, Changzhou Institute of Technology, Changzhou 213032, China.
  • Chen X; School of Chemical Engineering and Materials, Changzhou Institute of Technology, Changzhou 213032, China.
  • Chen Y; School of Chemical Engineering and Materials, Changzhou Institute of Technology, Changzhou 213032, China.
  • Cao ZY; College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, China.
J Org Chem ; 87(11): 7013-7021, 2022 06 03.
Article in En | MEDLINE | ID: mdl-35603573
ABSTRACT
Electrocatalytic three-component acylcyanation and aminocyanation of simple alkenes have been developed. The protocol features high functional group tolerance and can easily be scaled up. The key to success is to use an electrophilic cyanation source, enabling a broadened use of alkenes to aliphatic ones for acylcyanation.
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Full text: 1 Database: MEDLINE Main subject: Alkenes Language: En Journal: J Org Chem Year: 2022 Type: Article Affiliation country: China
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Add to My VHL
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PubMed Links
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Full text: 1 Database: MEDLINE Main subject: Alkenes Language: En Journal: J Org Chem Year: 2022 Type: Article Affiliation country: China