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Chemical Synthesis Enables the Configurational Determination of Myristriol, a Highly Oxygenated Phenylpropanoid from Myristica fragrans Houtt.
Xiao, Wen-Wen; Zhang, Hong-Lin; Wang, Chao-Fan; Chen, Yang; Zhan, Rui; Li, Dashan; Shao, Li-Dong.
Affiliation
  • Xiao WW; Yunnan Key Laboratory of Southern Medicinal Resources, School of Chinese Materia Medica, Yunnan University of Chinese Medicine, Kunming, 650500, P. R. China.
  • Zhang HL; Yunnan Key Laboratory of Southern Medicinal Resources, School of Chinese Materia Medica, Yunnan University of Chinese Medicine, Kunming, 650500, P. R. China.
  • Wang CF; School of Chemistry and Chemical Engineering, Yunnan Normal University, Kunming, 650050, P. R. China.
  • Chen Y; Yunnan Key Laboratory of Southern Medicinal Resources, School of Chinese Materia Medica, Yunnan University of Chinese Medicine, Kunming, 650500, P. R. China.
  • Zhan R; School of Chemistry and Chemical Engineering, Yunnan Normal University, Kunming, 650050, P. R. China.
  • Li D; Yunnan Key Laboratory of Southern Medicinal Resources, School of Chinese Materia Medica, Yunnan University of Chinese Medicine, Kunming, 650500, P. R. China.
  • Shao LD; Yunnan Key Laboratory of Southern Medicinal Resources, School of Chinese Materia Medica, Yunnan University of Chinese Medicine, Kunming, 650500, P. R. China.
Chem Biodivers ; 20(3): e202201075, 2023 Mar.
Article in En | MEDLINE | ID: mdl-36762483
ABSTRACT
A new phenylpropanoid, myristriol (1), along with 11 known ones were isolated from the seed kernel of Myristica fragrans Houtt. Their chemical structures were clearly elucidated by extensive spectroscopic analysis. In which, the relative configuration of 1 was finally determined as erythro-1 by comparison the NMR data of two synthetic erythro- and threo-diastereoisomers with that of natural 1.
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Full text: 1 Database: MEDLINE Main subject: Phenylpropionates / Myristica Language: En Journal: Chem Biodivers Journal subject: BIOQUIMICA / QUIMICA Year: 2023 Type: Article

Full text: 1 Database: MEDLINE Main subject: Phenylpropionates / Myristica Language: En Journal: Chem Biodivers Journal subject: BIOQUIMICA / QUIMICA Year: 2023 Type: Article