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Photoredox radical cyclization reaction of o-vinylaryl isocyanides with acyl chlorides to access 2,4-disubstituted quinolines.
Huang, Peng-Fei; Fu, Jia-Le; Huang, Jia-Jing; Xiong, Bi-Quan; Tang, Ke-Wen; Liu, Yu.
Affiliation
  • Huang PF; Department of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Yueyang 414006, China. 12021027@hnist.edu.cn.
  • Fu JL; Department of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Yueyang 414006, China. 12021027@hnist.edu.cn.
  • Huang JJ; Department of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Yueyang 414006, China. 12021027@hnist.edu.cn.
  • Xiong BQ; Department of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Yueyang 414006, China. 12021027@hnist.edu.cn.
  • Tang KW; Department of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Yueyang 414006, China. 12021027@hnist.edu.cn.
  • Liu Y; Department of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Yueyang 414006, China. 12021027@hnist.edu.cn.
Org Biomol Chem ; 22(3): 513-520, 2024 Jan 17.
Article in En | MEDLINE | ID: mdl-38131384
ABSTRACT
We herein report an efficient photoredox radical cyclization reaction of o-vinylaryl isocyanides with acyl chlorides to access a wide range of 2,4-disubstituted quinolines. Preliminary mechanism experiment results suggested that this reaction was initiated by an acyl radical generated from acyl chlorides through a single-electron-transfer (SET) process. This transformation showed good substrate suitability and functional group compatibility at room temperature.
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Full text: 1 Database: MEDLINE Language: En Journal: Org Biomol Chem Journal subject: BIOQUIMICA / QUIMICA Year: 2024 Type: Article Affiliation country: China
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Full text: 1 Database: MEDLINE Language: En Journal: Org Biomol Chem Journal subject: BIOQUIMICA / QUIMICA Year: 2024 Type: Article Affiliation country: China