Phosphine-catalyzed domino reaction for the synthesis of conjugated 2,3-dihydrofurans from allenoates and Nazarov reagents.
Chem Asian J
; 7(7): 1533-7, 2012 Jun.
Article
en En
| MEDLINE
| ID: mdl-22511612
ABSTRACT
A new domino reaction for Nazarov reagents An efficient approach was developed for the construction of highly functionalized conjugated 2,3-dihydrofuran skeletons. Nazarov reagents were used for the first time in a phosphine-catalyzed domino reaction and successfully used to construct five-membered ring compounds using alcohol as the solvent. DFT calculations indicate that alcohol is essential for the catalysis of the [1,2]-proton transfer.
Texto completo:
1
Bases de datos:
MEDLINE
Asunto principal:
Fosfinas
/
Furanos
/
Naftalenos
Idioma:
En
Revista:
Chem Asian J
Año:
2012
Tipo del documento:
Article
País de afiliación:
China