6-[(2-Hy-droxy-eth-yl)amino]-7H-dibenzo[de,h]quinolin-7-one.
Acta Crystallogr Sect E Struct Rep Online
; 68(Pt 7): o2004, 2012 Jul 01.
Article
en En
| MEDLINE
| ID: mdl-22807833
The title compound, C(18)H(14)N(2)O(2), is a new oxoisoaporphine derivative synthesized by alkyl-ation of 6-chloro-1-aza-benzanthrone. The oxoisoaporphine fragment deviates significantly from planarity with a dihedral angle of 5.1â
(1)° between the heterocycle and the remote benzene ring. The amino and oxo groups are involved in an intra-molecular N-Hâ¯O hydrogen bond, while the hy-droxy groups form inter-molecular O-Hâ¯N hydrogen bonds, which link pairs of mol-ecules into inversion dimers. In the dimer, two approximately parallel oxoisoaporphine fragments exhibit π-π inter-actions between the aromatic rings, the shortest centroid-centroid distance being 3.649â
(3)â
Å.
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Acta Crystallogr Sect E Struct Rep Online
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2012
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Article