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The first synthesis of Krempene B.
Shen, Li-Qun; Huang, Su-Yu; Tang, Yong; Lei, Fu-Hou.
Afiliación
  • Shen LQ; College of Chemistry and Chemical Engineering, Guangxi University for Nationalities, Key Laboratory of Development and Application of Forest Chemicals of Guangxi, Nanning 530006, China. liqunshen@126.com
Steroids ; 77(13): 1398-402, 2012 Nov.
Article en En | MEDLINE | ID: mdl-22989758
ABSTRACT
The synthesis of Krempene B, which can be isolated from the marine soft coral Cladiella krempfi, is achieved in 23.9% overall yield from commercially available 3ß-acetoxy-5-pregnen-20-one by 11 steps. Key transformations include the dienone-phenol rearrangement of steroids and Wittig reaction.
Asunto(s)

Texto completo: 1 Bases de datos: MEDLINE Asunto principal: Productos Biológicos / Diterpenos Idioma: En Revista: Steroids Año: 2012 Tipo del documento: Article País de afiliación: China

Texto completo: 1 Bases de datos: MEDLINE Asunto principal: Productos Biológicos / Diterpenos Idioma: En Revista: Steroids Año: 2012 Tipo del documento: Article País de afiliación: China