Combined bead polymerization and Cinchona organocatalyst immobilization by thiol-ene addition.
Beilstein J Org Chem
; 8: 1126-33, 2012.
Article
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| MEDLINE
| ID: mdl-23019440
ABSTRACT
In this work, we report an unusually concise immobilization of Cinchona organocatalysts using thiol-ene chemistry, in which catalyst immobilization and bead polymerization is combined in a single step. A solution of azo initiator, polyfunctional thiol, polyfunctional alkene and an unmodified Cinchona-derived organocatalyst in a solvent is suspended in water and copolymerized on heating by thiol-ene additions. The resultant spherical and gel-type polymer beads have been evaluated as organocatalysts in catalytic asymmetric transformations.
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MEDLINE
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En
Revista:
Beilstein J Org Chem
Año:
2012
Tipo del documento:
Article
País de afiliación:
Noruega