1-Ethyl-2-phenyl-3-[2-(tri-methyl-sil-yl)ethyn-yl]-1H-indole.
Acta Crystallogr Sect E Struct Rep Online
; 69(Pt 6): o921-2, 2013 Jun 01.
Article
en En
| MEDLINE
| ID: mdl-23795091
The title compound, C21H23NSi, was synthesized by Sonogashira-type reaction of 1-ethyl-3-iodo-2-phenyl-1H-indole with tri-methyl-silyl-acetyl-ene. The indole ring system is nearly planar [maximum atomic deviation = 0.0244â
(15)â
Å] and is oriented at a dihedral angle of 51.48â
(4)° with respect to the phenyl ring. The supramolecular aggregation is completed by weak C-Hâ¯π inter-actions of the methylene and phenyl groups with the benzene and pyrrole rings of the indole ring system. The methyl groups of the tri-methyl-silyl unit are equally disordered over two sets of sites.
Texto completo:
1
Bases de datos:
MEDLINE
Idioma:
En
Revista:
Acta Crystallogr Sect E Struct Rep Online
Año:
2013
Tipo del documento:
Article
País de afiliación:
Ucrania