Ammonia Storage by Reversible Host-Guest Site Exchange in a Robust Metal-Organic Framework.

Godfrey, Harry G W; da Silva, Ivan; Briggs, Lydia; Carter, Joseph H; Morris, Christopher G; Savage, Mathew; Easun, Timothy L; Manuel, Pascal; Murray, Claire A; Tang, Chiu C; Frogley, Mark D; Cinque, Gianfelice; Yang, Sihai; Schröder, Martin

Godfrey, Harry G W; da Silva, Ivan; Briggs, Lydia; Carter, Joseph H; Morris, Christopher G; Savage, Mathew; Easun, Timothy L; Manuel, Pascal; Murray, Claire A; Tang, Chiu C; Frogley, Mark D; Cinque, Gianfelice; Yang, Sihai; Schröder, Martin.

Afiliación

Godfrey HGW; School of Chemistry, University of Manchester, Oxford Road, Manchester, M13 9PL, UK.
da Silva I; ISIS Neutron and Muon Source, Rutherford Appleton Laboratory, Harwell Oxford, Didcot, OX11 0QX, UK.
Briggs L; School of Chemistry, University of Manchester, Oxford Road, Manchester, M13 9PL, UK.
Carter JH; School of Chemistry, University of Manchester, Oxford Road, Manchester, M13 9PL, UK.
Morris CG; Diamond Light Source, Harwell Science and Innovation Campus, Oxfordshire, OX11 0DE, UK.
Savage M; School of Chemistry, University of Manchester, Oxford Road, Manchester, M13 9PL, UK.
Easun TL; Diamond Light Source, Harwell Science and Innovation Campus, Oxfordshire, OX11 0DE, UK.
Manuel P; School of Chemistry, University of Manchester, Oxford Road, Manchester, M13 9PL, UK.
Murray CA; School of Chemistry, Cardiff University, Cardiff, CF10 3XQ, UK.
Tang CC; ISIS Neutron and Muon Source, Rutherford Appleton Laboratory, Harwell Oxford, Didcot, OX11 0QX, UK.
Frogley MD; Diamond Light Source, Harwell Science and Innovation Campus, Oxfordshire, OX11 0DE, UK.
Cinque G; Diamond Light Source, Harwell Science and Innovation Campus, Oxfordshire, OX11 0DE, UK.
Yang S; Diamond Light Source, Harwell Science and Innovation Campus, Oxfordshire, OX11 0DE, UK.
Schröder M; Diamond Light Source, Harwell Science and Innovation Campus, Oxfordshire, OX11 0DE, UK.

Angew Chem Int Ed Engl ; 57(45): 14778-14781, 2018 Nov 05.

Article en En | MEDLINE | ID: mdl-30098090

ABSTRACT

ABSTRACT

MFM-300(Al) shows reversible uptake of NH3 (15.7âmmol g-1 at 273âK and 1.0âbar) over 50 cycles with an exceptional packing density of 0.62âg cm-3 at 293âK. In situ neutron powder diffraction and synchrotron FTIR micro-spectroscopy on ND3 @MFM-300(Al) confirms reversible H/D site exchange between the adsorbent and adsorbate, representing a new type of adsorption interaction.

Palabras clave

MFM-300; ammonia; metal-organic framework; neutron diffraction; storage materials

Texto completo

Añadir a Mi BVS

Imprimir

XML

PubMed Links

Buscar en Google

Texto completo: 1 Bases de datos: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Año: 2018 Tipo del documento: Article País de afiliación: Reino Unido