A Conformationally Flexible Macrocyclic Dipyrrin Tetramer and Its Unsymmetrically Twisted Luminescent Zinc(II) Complex.
Inorg Chem
; 58(2): 995-998, 2019 Jan 22.
Article
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| MEDLINE
| ID: mdl-30556690
ABSTRACT
A macrocyclic dipyrrin tetramer containing flexible m-phenylene linkages and its tetranuclear zinc(II) complex were synthesized. The obtained complex has an unsymmetrical figure-of-eight structure because of the conformational flexibility of the macrocyclic framework. The first µ-hydroxo- and µ-acetato-bridged dinuclear zinc(II) dipyrrin complex structure is realized in the twisted macrocyclic complex. Furthermore, the complex exhibited an efficient emission in toluene and chloroform.
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MEDLINE
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En
Revista:
Inorg Chem
Año:
2019
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Article
País de afiliación:
Japón