A Conformationally Flexible Macrocyclic Dipyrrin Tetramer and Its Unsymmetrically Twisted Luminescent Zinc(II) Complex.

Hojo, Tomohiro; Matsuoka, Ryota; Nabeshima, Tatsuya

Hojo, Tomohiro; Matsuoka, Ryota; Nabeshima, Tatsuya.

Afiliación

Hojo T; Graduate School of Pure and Applied Sciences and Tsukuba Research Center for Energy Materials Science (TREMS) , University of Tsukuba , 1-1-1 Tennodai , Tsukuba , Ibaraki 305-8571 , Japan.
Matsuoka R; Graduate School of Pure and Applied Sciences and Tsukuba Research Center for Energy Materials Science (TREMS) , University of Tsukuba , 1-1-1 Tennodai , Tsukuba , Ibaraki 305-8571 , Japan.
Nabeshima T; Graduate School of Pure and Applied Sciences and Tsukuba Research Center for Energy Materials Science (TREMS) , University of Tsukuba , 1-1-1 Tennodai , Tsukuba , Ibaraki 305-8571 , Japan.

Inorg Chem ; 58(2): 995-998, 2019 Jan 22.

Article en En | MEDLINE | ID: mdl-30556690

ABSTRACT

ABSTRACT

A macrocyclic dipyrrin tetramer containing flexible m-phenylene linkages and its tetranuclear zinc(II) complex were synthesized. The obtained complex has an unsymmetrical figure-of-eight structure because of the conformational flexibility of the macrocyclic framework. The first µ-hydroxo- and µ-acetato-bridged dinuclear zinc(II) dipyrrin complex structure is realized in the twisted macrocyclic complex. Furthermore, the complex exhibited an efficient emission in toluene and chloroform.

Texto completo

Añadir a Mi BVS

Imprimir

XML

PubMed Links

Buscar en Google

Texto completo: 1 Bases de datos: MEDLINE Idioma: En Revista: Inorg Chem Año: 2019 Tipo del documento: Article País de afiliación: Japón