Strongly luminescent 5d/4f heterometal-organic macrocycles with open metal sites: post-assembly modification and sensing.
Dalton Trans
; 48(14): 4479-4483, 2019 Apr 02.
Article
en En
| MEDLINE
| ID: mdl-30865749
ABSTRACT
A series of strongly luminescent 5d/4f heterometal-organic macrocycles formulated as Ln2(Pt-L)2 have been constructed from a preformed cis-blocked alkynylplatinum metalloligand (Pt-L) and lanthanide (Ln = LaIII, EuIII, LuIII) ions. Open metal sites on the lanthanide centres of the heterometal-organic macrocycles facilitate not only the post-assembly modification leading to great enhancement of the luminescence, but also the displacement sensing toward toxic thiophosphonates.
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MEDLINE
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En
Revista:
Dalton Trans
Asunto de la revista:
QUIMICA
Año:
2019
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Article