N-Butyllithium-Treated Ti3C2Tx MXene with Excellent Pseudocapacitor Performance.
ACS Nano
; 13(8): 9449-9456, 2019 Aug 27.
Article
en En
| MEDLINE
| ID: mdl-31374174
ABSTRACT
MXenes, a family of two-dimensional (2D) transition-metal carbide and nitride materials, are supposed to be promising pseudocapacitive materials because of their high electronic conductivity and hydrophilic surfaces. MXenes, prepared by removing the "A" elements of their corresponding MAX phases by hydrofluoric acid (HF) or LiF-HCl etching, possess abundant terminal groups like -F, -OH, and -O groups. It has been proven that the MXenes with fewer -F terminal groups and more -O groups showed a higher pseudocapacitor performance. In organic reactions, -OH and -X (X = halogen) groups could turn to ether groups in strong nucleophilic reagent. Inspired by that, herein, we report an n-butyllithium-treated method to turn the -F and -OH terminal groups to -O groups on the Ti3C2Tx MXenes. Two types of Ti3C2Tx MXenes prepared by either HF or LiF-HCl etching were systematically investigated, and a comparison with the traditional KOH/NaOH/LiOH-treated method was also carried out. It is found that most of the -F terminal groups on the Ti3C2Tx MXenes can be successfully removed by n-butyllithium, and abundant -O terminal groups were formed. The n-butyllithium-treated Ti3C2Tx MXenes show promising applications in high-performance pseudocapacitors. A record high capacitance of 523 F g-1 at 2 mV s-1 was obtained for the n-butyllithium-treated Ti3C2Tx MXenes, and 96% capacity can remain even after 10â¯000 cycles.
Texto completo:
1
Bases de datos:
MEDLINE
Idioma:
En
Revista:
ACS Nano
Año:
2019
Tipo del documento:
Article
País de afiliación:
China