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Determination of nucleobase-pairing free energies from rotamer equilibria of 2-(methylamino)pyrimidines.
Stocek, Jakub Radek; Bártová, Katerina; Cechová, Lucie; Sála, Michal; Socha, Ondrej; Janeba, Zlatko; Dracínský, Martin.
Afiliación
  • Stocek JR; Institute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, Flemingovo nám. 2, 166 10, Prague, Czech Republic. dracinsky@uochb.cas.cz.
  • Bártová K; Institute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, Flemingovo nám. 2, 166 10, Prague, Czech Republic. dracinsky@uochb.cas.cz.
  • Cechová L; Institute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, Flemingovo nám. 2, 166 10, Prague, Czech Republic. dracinsky@uochb.cas.cz.
  • Sála M; Institute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, Flemingovo nám. 2, 166 10, Prague, Czech Republic. dracinsky@uochb.cas.cz.
  • Socha O; Institute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, Flemingovo nám. 2, 166 10, Prague, Czech Republic. dracinsky@uochb.cas.cz.
  • Janeba Z; Institute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, Flemingovo nám. 2, 166 10, Prague, Czech Republic. dracinsky@uochb.cas.cz.
  • Dracínský M; Institute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, Flemingovo nám. 2, 166 10, Prague, Czech Republic. dracinsky@uochb.cas.cz.
Chem Commun (Camb) ; 55(74): 11075-11078, 2019 Sep 21.
Article en En | MEDLINE | ID: mdl-31455961
ABSTRACT
A fast straightforward method for the determination of free energies of modified nucleobase pairing is proposed. The method is based on the nuclear magnetic resonance (NMR) spectroscopy monitoring of conformational changes of 2-(methylamino)-pyrimidines upon intermolecular binding.
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Texto completo: 1 Bases de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2019 Tipo del documento: Article País de afiliación: República Checa
Texto completo
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Texto completo: 1 Bases de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2019 Tipo del documento: Article País de afiliación: República Checa