The Synthesis Science of Targeted Vapor-Phase Metal-Organic Framework Postmodification.
J Am Chem Soc
; 142(1): 242-250, 2020 01 08.
Article
en En
| MEDLINE
| ID: mdl-31851505
ABSTRACT
The postmodification of metal organic frameworks (MOFs) affords exceedingly high surface area materials with precisely installed chemical features, which provide new opportunities for detailed structure-function correlation in the field of catalysis. Here, we significantly expand upon the number of vapor-phase postmodification processes reported to date through screening a library of atomic layer deposition (ALD) precursors, which span metals across the periodic table and which include ligands from four distinct precursor classes. With a large library of precursors and synthesis conditions, we discern trends in the compatibility of precursor classes for well-behaved ALD in MOFs (AIM) and identify challenges and solutions to more precise postsynthetic modification.
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1
Bases de datos:
MEDLINE
Asunto principal:
Estructuras Metalorgánicas
/
Gases
Idioma:
En
Revista:
J Am Chem Soc
Año:
2020
Tipo del documento:
Article