Facile synthesis of the crescent-like SnS nanocrystals capped by polyvinyl pyrrolidone and its performance of adsorbing dyes.

ABSTRACT

With using Sn2+ as tin source, l-cysteine as sulphur source and polyvinyl pyrrolidone (PVP, Mw = 1300000) as surfactant, a novel three-dimensional and crescent-like SnS nanocrystal (NCs) was successfully synthesized in a one-pot hydrothermal method. The as-prepared SnS NCs displayed uniform crescent-like morphological structure, and demonstrated excellent efficiency for the adsorption of cationic dyes such as rhodamine B (RhB) and methylene blue (MB). Kinetic analysis indicated that the adsorption process followed the pseudo second-order model, and the maximum capacity of the SnS NCs to adsorb MB was determined by Langmuir equation to be 252 mg⋅g-1 at 298 K. The pH dependence of SnS NCs on the adsorption of cationic dyes and the characterization of zeta potential jointly suggested the existence of electrostatic attraction in the process. Overall, this study showed that electrostatic field of functional groups and the capping of PVP could significantly enhance the adsorption performance of the SnS NCs, and also provides a novel insight into the development of highly efficient inorganic adsorbents for cationic dyes.