Photoinduced boron atom insertion of benzocyclobutene forming an unprecedented fused boron heterocyclic radical.
Chem Commun (Camb)
; 59(11): 1529-1532, 2023 Feb 02.
Article
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| MEDLINE
| ID: mdl-36661048
ABSTRACT
Two novel boron heterocyclic radicals, an addition bicyclo[4.2.1]octa-1,3,5-trien-1-yl-borane radical (A) and an insertion 7-1H-borolo[1,2-a]borinine radical (B), were synthesized, and characterized in the reaction of atomic boron with benzocyclobutene. Species B involving a fused boron heterocyclic was spectroscopically characterized for the first time. This work is a new approach for boron-mediated molecular editing and the synthesis of fused boron heterocyclic compounds.
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Bases de datos:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Asunto de la revista:
QUIMICA
Año:
2023
Tipo del documento:
Article
País de afiliación:
China