Synthesis of <i>o</i>-Sulfinylanilines from <i>N</i>-Alkyl Sulfoximines and Arynes.

Wang, Xianliang; Frings, Marcus; Rissanen, Kari; Bolm, Carsten

Synthesis of o-Sulfinylanilines from N-Alkyl Sulfoximines and Arynes.

Wang, Xianliang; Frings, Marcus; Rissanen, Kari; Bolm, Carsten.

Afiliación

Wang X; Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany.
Frings M; Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany.
Rissanen K; University of Jyvaskyla, Department of Chemistry, FI-40014 Jyväskylä, Finland.
Bolm C; Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany.

J Org Chem ; 88(4): 2666-2669, 2023 Feb 17.

Article en En | MEDLINE | ID: mdl-36701544

RESUMEN

N-Alkyl sulfoximines react with arynes generated in situ under mild conditions providing o-sulfinylanilines in good yields. The transformation is characterized by a broad substrate scope and a good functional group tolerance. The structure of a reaction product was confirmed by single-crystal X-ray diffraction.

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Texto completo: 1 Bases de datos: MEDLINE Idioma: En Revista: J Org Chem Año: 2023 Tipo del documento: Article País de afiliación: Alemania