Access to Azetidines via Gold Mediated Energy Transfer Photocatalysis.
Org Lett
; 25(9): 1403-1408, 2023 Mar 10.
Article
en En
| MEDLINE
| ID: mdl-36847204
ABSTRACT
The area of energy transfer photocatalysis to generate four-membered rings is experiencing an unprecedented level of activity. Here, we report an operationally simple method toward azetidines from 2-isoxasoline-3-carboxylates and alkenes, using [Au(cbz)(NHC)] complexes as photocatalysts. The procedure enables the reaction for a wide range of substrates. Mechanistic studies confirm the energy transfer pathway. This contribution adds to the earlier reported use of these gold catalysts as a potentially versatile tool in energy transfer chemistry and catalysis.
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Bases de datos:
MEDLINE
Idioma:
En
Revista:
Org Lett
Asunto de la revista:
BIOQUIMICA
Año:
2023
Tipo del documento:
Article
País de afiliación:
Bélgica