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Prussian Blue Analogues for Sodium-Ion Battery Cathodes: A Review of Mechanistic Insights, Current Challenges, and Future Pathways.
Xiao, Yang; Xiao, Jun; Zhao, Hangkai; Li, Jiayi; Zhang, Guilai; Zhang, Dingyi; Guo, Xin; Gao, Hong; Wang, Yong; Chen, Jun; Wang, Guoxiu; Liu, Hao.
Afiliación
  • Xiao Y; Joint International Laboratory on Environmental and Energy Frontier Materials, School of Environmental and Chemical Engineering, Shanghai University, Shanghai, 200444, China.
  • Xiao J; Faculty of Materials Science and Energy Engineering/, Institute of Technology for Carbon Neutrality, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen, Guangdong, 518055, China.
  • Zhao H; Joint International Laboratory on Environmental and Energy Frontier Materials, School of Environmental and Chemical Engineering, Shanghai University, Shanghai, 200444, China.
  • Li J; Joint International Laboratory on Environmental and Energy Frontier Materials, School of Environmental and Chemical Engineering, Shanghai University, Shanghai, 200444, China.
  • Zhang G; Joint International Laboratory on Environmental and Energy Frontier Materials, School of Environmental and Chemical Engineering, Shanghai University, Shanghai, 200444, China.
  • Zhang D; Joint International Laboratory on Environmental and Energy Frontier Materials, School of Environmental and Chemical Engineering, Shanghai University, Shanghai, 200444, China.
  • Guo X; Faculty of Materials Science and Energy Engineering/, Institute of Technology for Carbon Neutrality, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen, Guangdong, 518055, China.
  • Gao H; Joint International Laboratory on Environmental and Energy Frontier Materials, School of Environmental and Chemical Engineering, Shanghai University, Shanghai, 200444, China.
  • Wang Y; Joint International Laboratory on Environmental and Energy Frontier Materials, School of Environmental and Chemical Engineering, Shanghai University, Shanghai, 200444, China.
  • Chen J; Intelligent Polymer Research Institute, Innovation Campus, University of Wollongong, Squires Way, North Wollongong, NSW, 2500, Australia.
  • Wang G; Centre for Clean Energy Technology, University of Technology Sydney, Broadway, Sydney, NSW, 2007, Australia.
  • Liu H; Centre for Clean Energy Technology, University of Technology Sydney, Broadway, Sydney, NSW, 2007, Australia.
Small ; 20(35): e2401957, 2024 Aug.
Article en En | MEDLINE | ID: mdl-38682730
ABSTRACT
Prussian blue analogues (PBAs) have emerged as highly promising cathode materials for sodium-ion batteries (SIBs) due to their affordability, facile synthesis, porous framework, and high theoretical capacity. Despite their considerable potential, practical applications of PBAs face significant challenges that limit their performance. This review offers a comprehensive retrospective analysis of PBAs' development history as cathode materials, delving into their reaction mechanisms, including charge compensation and ion diffusion mechanisms. Furthermore, to overcome these challenges, a range of improvement strategies are proposed, encompassing modifications in synthesis techniques and enhancements in structural stability. Finally, the commercial viability of PBAs is examined, alongside discussions on advanced synthesis methods and existing concerns regarding cost and safety, aiming to foster ongoing advancements of PBAs for practical SIBs.
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Texto completo: 1 Bases de datos: MEDLINE Idioma: En Revista: Small Asunto de la revista: ENGENHARIA BIOMEDICA Año: 2024 Tipo del documento: Article País de afiliación: China

Texto completo: 1 Bases de datos: MEDLINE Idioma: En Revista: Small Asunto de la revista: ENGENHARIA BIOMEDICA Año: 2024 Tipo del documento: Article País de afiliación: China