Visible light-promoted [3+2] cyclization reaction of vinyl azides with perfluoroalkyl-substituted-imidoyl sulfoxonium ylides.

Yang, Ming; Meng, Yu-Xuan; Mehfooz, Haroon; Zhao, Yu-Long

Yang, Ming; Meng, Yu-Xuan; Mehfooz, Haroon; Zhao, Yu-Long.

Afiliación

Yang M; Jilin Province Key Laboratory of Organic Functional Molecular Design & Synthesis, Department of Chemistry, Northeast Normal University, Changchun 130024, China. zhaoyl351@nenu.edu.cn.
Meng YX; Jilin Province Key Laboratory of Organic Functional Molecular Design & Synthesis, Department of Chemistry, Northeast Normal University, Changchun 130024, China. zhaoyl351@nenu.edu.cn.
Mehfooz H; Jilin Province Key Laboratory of Organic Functional Molecular Design & Synthesis, Department of Chemistry, Northeast Normal University, Changchun 130024, China. zhaoyl351@nenu.edu.cn.
Zhao YL; Jilin Province Key Laboratory of Organic Functional Molecular Design & Synthesis, Department of Chemistry, Northeast Normal University, Changchun 130024, China. zhaoyl351@nenu.edu.cn.

Chem Commun (Camb) ; 60(41): 5407-5410, 2024 May 16.

Article en En | MEDLINE | ID: mdl-38683050

ABSTRACT

ABSTRACT

Visible-light-induced [3+2] cyclization of vinyl azides with perfluoroalkyl-substituted imidoyl sulfoxonium ylides has been developed for the first time. In this transformation, perfluoroalkyl-substituted imidoyl sulfoxonium ylides are firstly employed as a carbon radical precursor under visible light irradiation, providing a new and efficient method for the construction of perfluoroalkyl-substituted 1-pyrrolines.

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Texto completo: 1 Bases de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2024 Tipo del documento: Article País de afiliación: China

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