The development of Giant reed biochar for adsorption of Basic Blue 41 and Eriochrome Black T. azo dyes from wastewater.

ABSTRACT

The textile industry is discharging high concentrations of anionic and cationic azo dyes into the nearby environment, which can cause adverse effects on public health, and the aquatic environment. Therefore, this study aimed to develop giant reed biochar and apply for the removal of Basic blue 41 (BB41) and Eriochrome black T (EBT) azo dyes from water. Characterization techniques such as BET surface area analyzer, Fourier-transform infrared spectroscopy (FT-IR), Raman spectroscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM), and thermal gravimetric analyzer (TGA) were applied for biochar description. The biochar exhibits a high fixed carbon content (80.4%), a low ash content (3.8%), a large surface area (429.0 m2/g), and good thermal stability. High removal efficiencies of BB41 98.6% and EBT 82.5% were recorded at the specific experimental condition. The experimental data were fitted with the Langmuir isotherm model at R2 0.99 for both dyes whereas the adsorption kinetics revealed the pseudo-second-order kinetics at R2 ∼ 1 and 0.99 for BB41 and EBT, respectively. Furthermore, four regenerations of biochar with adsorption performances of BB41 and EBT dyes were found to be 94.7% and 79.1%, respectively. Finally, this adsorbent can be considered an economically viable material for the removal of synthetic dyes from wastewater systems. In conclusion, the study findings showed that the adsorbent material is promising to apply for water and wastewater treatment but still, the study of adsorption interaction and modifications of the surface functionalities are essential to accommodate multipollutant removal from real water systems.