Studies toward the total synthesis of popolohuanone E: enantioselective synthesis of 8-O-methylpopolohuanone E.
Org Lett
; 3(17): 2701-4, 2001 Aug 23.
Article
em En
| MEDLINE
| ID: mdl-11506613
ABSTRACT
[structure see text]. 8-O-methylpopolohuanone E (2) was synthesized in a highly convergent manner starting from the cis-fused decalin derivative accessible from the (-)-Wieland-Miescher ketone analogue. The synthetic method features a biogenetic-type annulation of the phenolic and quinone segments to regioselectively construct the central tricyclic ring system as the key step.
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Bases de dados:
MEDLINE
Assunto principal:
Sesquiterpenos
/
Inibidores Enzimáticos
Idioma:
En
Revista:
Org Lett
Assunto da revista:
BIOQUIMICA
Ano de publicação:
2001
Tipo de documento:
Article
País de afiliação:
Japão