Controlled diastereoselectivity at the alkene-geometry through selective encapsulation: E-Z photoisomerization of oxazolidinone-functionalized enecarbamates within hydrophobic nano-cavities.
Chem Commun (Camb)
; (8): 819-21, 2007 Feb 28.
Article
em En
| MEDLINE
| ID: mdl-17308642
ABSTRACT
Photoisomerization of encapsulated Z-enecarbamates within the hydrophobic chiral cavities of gamma-CD showed higher diastereoselectivities in the photoproducts than those obtained in solution. The selective encapsulation of the enecarbamates and the following isomerization process are both diastereoselectively controlled by gamma-CD.
Buscar no Google
Bases de dados:
MEDLINE
Assunto principal:
Carbamatos
/
Oxazolidinonas
/
Alcenos
Idioma:
En
Revista:
Chem Commun (Camb)
Assunto da revista:
QUIMICA
Ano de publicação:
2007
Tipo de documento:
Article
País de afiliação:
Estados Unidos