Biomimetic seleninates and selenonates.
J Am Chem Soc
; 130(29): 9234-5, 2008 Jul 23.
Article
em En
| MEDLINE
| ID: mdl-18576651
ABSTRACT
The synthesis of a variety of pyranose-, nucleoside-, (amino acid)-, and polyhydric-based seleninic and selenonic acids by DMDO oxidation of the corresponding selenoesters is reported, as well as some unusual coupling reactions of the seleninate and selenonate functionality with biological nucleophilic groups (sulfhydryl, indole, phenol, imidazole, carboxamide) that are found in proteins and enzyme active sites.
Texto completo:
1
Bases de dados:
MEDLINE
Assunto principal:
Compostos Organosselênicos
/
Materiais Biomiméticos
Idioma:
En
Revista:
J Am Chem Soc
Ano de publicação:
2008
Tipo de documento:
Article
País de afiliação:
Estados Unidos