Rhodium-catalyzed asymmetric hydroalkoxylation and hydrosulfenylation of diphenylphosphinylallenes.

Kawamoto, Takahiro; Hirabayashi, Sho; Guo, Xun-Xiang; Nishimura, Takahiro; Hayashi, Tamio

Kawamoto, Takahiro; Hirabayashi, Sho; Guo, Xun-Xiang; Nishimura, Takahiro; Hayashi, Tamio.

Afiliação

Kawamoto T; Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan.

Chem Commun (Camb) ; (24): 3528-30, 2009 Jun 28.

Article em En | MEDLINE | ID: mdl-19521596

RESUMO

The rhodium-catalyzed intermolecular asymmetric hydroalkoxylation and hydrosulfenylation of diphenylphosphinylallenes gave chiral allylic phosphine oxides substituted with vinyl ether and thioether moieties in high yields with high enantioselectivities.

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Texto completo: 1 Bases de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2009 Tipo de documento: Article País de afiliação: Japão

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